SiC-based ceramics with remarkable electrical conductivity prepared by ultrafast high-temperature sintering

被引:15
|
作者
Li, Hong Wei [1 ]
Zhao, Yi Peng [1 ]
Chen, Guo Qing [1 ,2 ]
Li, Ming Hao [1 ]
Wei, Zhi Fan [1 ]
Fu, Xue Song [1 ]
Zhou, Wen Long [1 ]
机构
[1] Dalian Univ Technol, Sch Mat Sci & Engn, Key Lab Solidificat Control & Digital Preparat Tec, Dalian 116085, Peoples R China
[2] Dalian Univ Technol, Dalian, Peoples R China
基金
中国国家自然科学基金;
关键词
Ultrafast high-temperature sintering; SiC; Melt electrolysis; Redox reaction; Electrical conductivity; SILICON-CARBIDE CERAMICS; ELECTROCHEMICAL FORMATION; THERMAL-PROPERTIES; YTTRIUM; ALLOYS;
D O I
10.1016/j.jeurceramsoc.2022.12.025
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
SiC-based ceramics with high electrical conductivity are applied widely as electrode materials and semiconductor materials. In this study, a SiC-based ceramic with relative density of 96% was prepared by ultrafast high -temperature sintering (UHS) at 2000 degrees C (with a heating rate of 1000 degrees C/min) for 40 s. The resistivity of as UHS-ed SiC-based ceramic was 1/15 of that prepared by the pressureless sintering. We found that the compo-nents of as-sintered body (SiC, Si and Y3Si5) by UHS were different from those (SiC and YAG) prepared by the pressureless sintering. The reason for the remarkable increase of the electrical conductivity of UHS-ed body was that the Si with higher electrical conductivity than SiC had emerged. Besides, the reaction mechanism was proposed and the unusual composition of the SiC-based ceramic sintered by UHS may also provide new reference for the application of SiC in specific fields.
引用
收藏
页码:2269 / 2274
页数:6
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