SiC-based ceramics with remarkable electrical conductivity prepared by ultrafast high-temperature sintering

被引:15
|
作者
Li, Hong Wei [1 ]
Zhao, Yi Peng [1 ]
Chen, Guo Qing [1 ,2 ]
Li, Ming Hao [1 ]
Wei, Zhi Fan [1 ]
Fu, Xue Song [1 ]
Zhou, Wen Long [1 ]
机构
[1] Dalian Univ Technol, Sch Mat Sci & Engn, Key Lab Solidificat Control & Digital Preparat Tec, Dalian 116085, Peoples R China
[2] Dalian Univ Technol, Dalian, Peoples R China
基金
中国国家自然科学基金;
关键词
Ultrafast high-temperature sintering; SiC; Melt electrolysis; Redox reaction; Electrical conductivity; SILICON-CARBIDE CERAMICS; ELECTROCHEMICAL FORMATION; THERMAL-PROPERTIES; YTTRIUM; ALLOYS;
D O I
10.1016/j.jeurceramsoc.2022.12.025
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
SiC-based ceramics with high electrical conductivity are applied widely as electrode materials and semiconductor materials. In this study, a SiC-based ceramic with relative density of 96% was prepared by ultrafast high -temperature sintering (UHS) at 2000 degrees C (with a heating rate of 1000 degrees C/min) for 40 s. The resistivity of as UHS-ed SiC-based ceramic was 1/15 of that prepared by the pressureless sintering. We found that the compo-nents of as-sintered body (SiC, Si and Y3Si5) by UHS were different from those (SiC and YAG) prepared by the pressureless sintering. The reason for the remarkable increase of the electrical conductivity of UHS-ed body was that the Si with higher electrical conductivity than SiC had emerged. Besides, the reaction mechanism was proposed and the unusual composition of the SiC-based ceramic sintered by UHS may also provide new reference for the application of SiC in specific fields.
引用
收藏
页码:2269 / 2274
页数:6
相关论文
共 50 条
  • [1] HIGH-TEMPERATURE CORROSION OF SIC-BASED CERAMICS IN CHLORINE CONTAINING ENVIRONMENTS
    MCNALLAN, MJ
    IP, SY
    SAAM, S
    LIANG, WW
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1985, 132 (08) : C364 - C364
  • [2] Ultrafast high-temperature sintering and densification of ZrC-based ceramics
    Zhang, Bowen
    Hu, Mengchen
    Zhong, Fugang
    Zhang, Shengping
    Yang, Zewei
    Qiu, Xinchao
    Xu, Jianbo
    Jun, Ou-Yang
    Zhang, Yue
    Zhu, Benpeng
    Yang, Xiaofei
    Chen, Shi
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2024, 44 (10) : 5569 - 5578
  • [3] Ultrafast high-temperature sintering of lanthanum-chromite-based ceramics
    Guo, Rui-Fen
    Zhao, Zhi-Tao
    Shen, Ping
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2022, 42 (15) : 7072 - 7080
  • [4] Liquid-phase sintering of SiC-based ceramics
    Izhevskyi, VA
    Genova, LA
    Bressiani, JC
    Bressiani, AHA
    ADVANCED POWDER TECHNOLOGY II, 2001, 189-1 : 173 - 180
  • [5] HIGH-TEMPERATURE ELECTRICAL-CONDUCTIVITY OF AIN CERAMICS
    GROEN, WA
    VANHAL, PF
    BRITISH CERAMIC TRANSACTIONS, 1994, 93 (05): : 192 - 195
  • [6] Structure, properties and toughening mechanisms of SiCw/SiC ceramics prepared by high-temperature and high-pressure sintering
    Xiao, Changjiang
    Zheng, Haoyu
    Li, Xiang
    Tang, Lihui
    MATERIALS TODAY COMMUNICATIONS, 2025, 44
  • [7] High-temperature thermal conductivity of biomorphic SiC/Si ceramics
    Ramirez-Rico, J.
    Singh, M.
    Zhu, D.
    Martinez-Fernandez, J.
    JOURNAL OF MATERIALS SCIENCE, 2017, 52 (17) : 10038 - 10046
  • [8] High-temperature thermal conductivity of biomorphic SiC/Si ceramics
    J. Ramírez-Rico
    M. Singh
    D. Zhu
    J. Martínez-Fernández
    Journal of Materials Science, 2017, 52 : 10038 - 10046
  • [9] Low-Temperature Sintering of SHS-Produced SiC-Based Porous Ceramics
    Kirillov, A. O.
    Kapustin, R. D.
    Uvarov, V. I.
    Boyarchenko, O. D.
    INTERNATIONAL JOURNAL OF SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS, 2024, 33 (04) : 280 - 286
  • [10] PRESSURELESS SINTERING AND HIGH-TEMPERATURE STRENGTH OF SIC-AIN CERAMICS
    LI, JF
    WATANABE, R
    NIPPON SERAMIKKUSU KYOKAI GAKUJUTSU RONBUNSHI-JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 1994, 102 (08): : 727 - 731