Solid polymer electrolytes from NaAlg: PVA: effect of ammonium thiocyanate on ionic conductivity

被引：9
|
作者：
Jansi, R. [1 ,2 ]
Shenbagavalli, S. [1 ,2 ]
Revathy, M. S. [1 ]
Deepalakshmi, S. [2 ,3 ]
机构：
[1] Kalasalingam Acad Res & Educ, Sch Adv Sci, Dept Phys, Virudunagar 626126, Tamil Nadu, India
[2] Kalasalingam Acad Res & Educ, Int Res Ctr, Multifunct Mat Lab, Virudunagar 626126, Tamil Nadu, India
[3] Rajapalayam Rajus Coll, Dept Comp Sci, Rajapalayam, India
来源：
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS | 2023年 / 34卷 / 06期
关键词：
AMINO-ACID PROLINE; ELECTRICAL-PROPERTIES; CHITOSAN; MEMBRANE; PECTIN;
D O I：
10.1007/s10854-023-09825-6
中图分类号：
TM [电工技术]; TN [电子技术、通信技术];
学科分类号：
0808 ; 0809 ;
摘要：
PVA: NaAlg with NH4SCN(different wt. %) solid polymer electrolytes(SPE) were prepared by solution casting technique. XRD and FTIR investigations confirmed, polymer's amorphous character and complexation with salt. The Nyquist plot of PVA: NaAlg: NH4SCN(15 wt.%) SPE showed a significant ionic conductivity of 2.27 x 10(-6)S=cm. The relaxation time was1.08 9 10(-4 )s. Linear Sweep Voltammetry studies indicated that prepared SPE have an electro-chemical stability window of 0.7 V. The Cyclic voltammetry investigation exhibited faradaic behavior. Based on these studies, the inclusion of ammonium salt in this reported hybrid polymer blend could be a potential SPE for elec-trochemical devices.
引用
收藏
页数：13
相关论文
共 50 条
  • [41] Effect of Polymer Topology on Microstructure, Segmental Dynamics, and Ionic Conductivity in PEO/PMMA-Based Solid Polymer Electrolytes
    Bakar, Recep
    Darvishi, Saeid
    Li, Tianyu
    Han, Mertcan
    Aydemir, Umut
    Nizamoglu, Sedat
    Hong, Kunlun
    Senses, Erkan
    ACS APPLIED POLYMER MATERIALS, 2022, 4 (01) : 179 - 190
  • [42] The effect of hard segment content on ionic conductivity of poly(ether urethane)-based solid polymer electrolytes
    Young-Deok Kim
    Min-Kyung Kim
    Nam-Ju Jo
    Ionics, 2011, 17 : 805 - 810
  • [43] Ionic liquid incorporated SPEEK/Chitosan solid polymer electrolytes: ionic conductivity and dielectric study
    Mesut Yılmazoğlu
    Fatih Bayıroğlu
    Hamit Erdemi
    Ufuk Abaci
    H. Yuksel Guney
    Journal of Solid State Electrochemistry, 2023, 27 : 1143 - 1154
  • [44] Ionic liquid incorporated SPEEK/Chitosan solid polymer electrolytes: ionic conductivity and dielectric study
    Yilmazoglu, Mesut
    Bayiroglu, Fatih
    Erdemi, Hamit
    Abaci, Ufuk
    Guney, H. Yuksel
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2023, 27 (05) : 1143 - 1154
  • [45] The effect of hard segment content on ionic conductivity of poly(ether urethane)-based solid polymer electrolytes
    Kim, Young-Deok
    Kim, Min-Kyung
    Jo, Nam-Ju
    IONICS, 2011, 17 (09) : 805 - 810
  • [46] Enhancement in Ionic Conductivity on Solid Polymer Electrolytes containing large conducting species
    Praveen, D.
    Damle, Ramakrishna
    DAE SOLID STATE PHYSICS SYMPOSIUM 2015, 2016, 1731
  • [47] High ionic conductivity of all-solid polymer electrolytes based on polyorganophosphazenes
    Zhou, Shuhua
    Fang, Shibi
    EUROPEAN POLYMER JOURNAL, 2007, 43 (08) : 3695 - 3700
  • [48] Enhancement Mechanism of Intermolecular Interaction on Ionic Conductivity of Composite Solid Polymer Electrolytes
    Wu H.
    Chen W.
    Yang J.
    Liu Y.
    Cai L.
    Cao Q.
    Hu L.
    Li H.
    Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2021, 37 (08): : 145 - 153
  • [49] Structural dynamics and ionic conductivity of amorphous type plasticized solid polymer electrolytes
    Choudhary, Shobhna
    Sengwa, R. J.
    INDIAN JOURNAL OF PURE & APPLIED PHYSICS, 2016, 54 (03) : 159 - 169
  • [50] Software for Evaluating Ionic Conductivity of Inorganic-Polymer Composite Solid Electrolytes
    Ding, Yuqing
    He, Bing
    Wang, Da
    Avdeev, Maxim
    Li, Yajie
    Shi, Siqi
    ENERGY MATERIAL ADVANCES, 2023, 4
12345