Electrochemical Incorporation of Electrophiles into the Biomass-Derived Platform Molecule 5-(Chloromethyl)furfural

被引：2
|
作者：
Ling, Huitao [1 ]
Miao, Haoqian [1 ]
Cao, Zhiling [1 ]
Mascal, Mark [1 ]
机构：
[1] Univ Calif Davis, Dept Chem, 1 Shields Ave, Davis, CA 95616 USA
来源：
CHEMSUSCHEM | 2023年 / 16卷 / 05期
关键词：
biobased products; carbon dioxide fixation; 5-(chloromethyl)furfural; electrochemistry; electrosynthesis; platform molecules; CARBON-DIOXIDE; CARBOXYLATION; CELLULOSE; CO2;
D O I：
10.1002/cssc.202201787
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The 5-(chloromethyl)furfural (CMF) derivative ethyl 5-(chloromethyl)furan-2-carboxylate undergoes two-electron electrochemical reduction in a simple, undivided cell to give the corresponding furylogous enolate anion, which can either be quenched with carbon dioxide to give a 5-(carboxymethyl)furan-2-carboxylate or with hydrogen ion to give a 5-methylfuran-2-carboxylate, thereby expanding the derivative scope of CMF as a biobased platform molecule.
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页数：5
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