Electrochemical Incorporation of Electrophiles into the Biomass-Derived Platform Molecule 5-(Chloromethyl)furfural

被引：2

作者：

Ling, Huitao ^{[1
]}

Miao, Haoqian ^{[1
]}

Cao, Zhiling ^{[1
]}

Mascal, Mark ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, 1 Shields Ave, Davis, CA 95616 USA

来源：

CHEMSUSCHEM | 2023年 / 16卷 / 05期

关键词：

biobased products; carbon dioxide fixation; 5-(chloromethyl)furfural; electrochemistry; electrosynthesis; platform molecules; CARBON-DIOXIDE; CARBOXYLATION; CELLULOSE; CO2;

D O I：

10.1002/cssc.202201787

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 5-(chloromethyl)furfural (CMF) derivative ethyl 5-(chloromethyl)furan-2-carboxylate undergoes two-electron electrochemical reduction in a simple, undivided cell to give the corresponding furylogous enolate anion, which can either be quenched with carbon dioxide to give a 5-(carboxymethyl)furan-2-carboxylate or with hydrogen ion to give a 5-methylfuran-2-carboxylate, thereby expanding the derivative scope of CMF as a biobased platform molecule.

引用

页数：5

共 50 条

[21] Efficient preparation of hybrid biofuels from biomass-derived 5-(acetoxymethyl)furfural and petroleum-derived aromatic hydrocarbons
Yadav, Abhishek Kumar
Bhat, Navya Subray
Kaushik, Sonal
Seikh, Asiful H.
Dutta, Saikat
RSC ADVANCES, 2024, 14 (05) : 3096 - 3103
[22] A divergent approach for the synthesis of (hydroxymethyl)furfural (HMF) from spent aromatic biomass-derived (chloromethyl)furfural (CMF) as a renewable feedstock
Singh, Mangat
Pandey, Nishant
Mishra, Bhuwan B.
RSC ADVANCES, 2020, 10 (73) : 45081 - 45089
[23] Synthesis of ranitidine (Zantac) from cellulose-derived 5-(chloromethyl)furfural
Mascal, Mark
Dutta, Saikat
GREEN CHEMISTRY, 2011, 13 (11) : 3101 - 3102
[24] Catalyst development for electrochemical hydrogenation of biomass-derived platform molecules
Zhang, Kaidi
Sun, Yiwei
Chen, Ziyao
Dong, Mengyang
Fu, Huaiqin
Xu, Yiming
Zou, Yu
Hu, Mengqing
Fu, Bo
Wang, Xinyu
Ahmad, Waseem
Wang, Liang
Zhang, Lei
Zhou, Ming
Wang, Yun
Yin, Huajie
Liu, Porun
Zhao, Huijun
CHEMICAL PHYSICS REVIEWS, 2024, 5 (04):
[25] Advances on the catalytic hydrogenation of biomass-derived furfural and 5-hydroxymethylfurfural
Zhang J.
Li D.-N.
Yuan H.-R.
Wang S.-R.
Chen Y.
Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2021, 49 (12): : 1752 - 1767
[26] Extraction of Furfural and Furfural/5-Hydroxymethylfurfural from Mixed Lignocellulosic Biomass-Derived Feedstocks
Wang, Zhaoxing
Bhattacharyya, Souryadeep
Vlachos, Dionisios G.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2021, 9 (22) : 7489 - 7498
[27] Reduced metal nanocatalysts for selective electrochemical hydrogenation of biomass-derived 5-(hydroxymethyl)furfural to 2,5-bis(hydroxymethyl)furan in ambient conditions
Muchharla, Baleeswaraiah
Dikshit, Moumita
Pokharel, Ujjwal
Garimella, Ravindranath
Adedeji, Adetayo
Kumar, Kapil
Cao, Wei
Elsayed-Ali, Hani
Sadasivuni, Kishor Kumar
Al-Dhabi, Naif Abdullah
Kumar, Sandeep
Kumar, Bijandra
FRONTIERS IN CHEMISTRY, 2023, 11
[28] Efficient synthesis of the liquid fuel 2,5-dimethylfuran from biomass derived 5-(chloromethyl)furfural at room temperature
Chen, Binglin
Feng, Yunchao
Huang, Renjie
Yang, Shibo
Li, Zheng
Sperry, Jonathan
Yang, Shuliang
Tang, Xing
Sun, Yong
Lin, Lu
Zeng, Xianhai
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2022, 318
[29] Kinetics and mechanism for electrochemical ammoxidation of furfural to biomass-derived nitrile over CoSe electrocatalyst
Xu, Zhongmou
Chen, Jinzhu
CHEMICAL ENGINEERING JOURNAL, 2024, 486
[30] Continuous electrochemical oxidation of biomass derived 5-(hydroxymethyl)furfural into 2,5-furandicarboxylic acid
R. Latsuzbaia
R. Bisselink
A. Anastasopol
H. van der Meer
R. van Heck
M. Segurola Yagüe
M. Zijlstra
M. Roelands
M. Crockatt
E. Goetheer
E. Giling
Journal of Applied Electrochemistry, 2018, 48 : 611 - 626

← 1 2 3 4 5 →