Coinage metal complexes of BN analogues of m-terphenyl ligands

被引：1
|
作者：
Lamprecht, Anna [1 ,2 ]
Lindl, Felix [1 ,2 ]
Endres, Lukas [1 ,2 ]
Krummenacher, Ivo [1 ,2 ]
Braunschweig, Holger [1 ,2 ]
机构：
[1] Julius Maximilians Univ Wurzburg, Inst Inorgan Chem, D-97074 Wurzburg, Germany
[2] Julius Maximilians Univ Wurzburg, Inst Sustainable Chem & Catalysis Boron, D-97074 Wurzburg, Germany
来源：
CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 67期
关键词：
COMPOUND;
D O I：
10.1039/d3cc03467d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the synthesis of a series of group 11 metal complexes with sterically demanding anionic nitrogen ligands based on the 1,2-azaborinine motif. The ligands, which share structural similarities with m-terphenyls, have been used to stabilize two-coordinate phosphine complexes and dimeric complexes with close contacts between the metal centers. Spectroscopic, crystallographic, and theoretical investigations reveal close parallels to the related m-terphenyl complexes, including metallophilic interactions in the dimers.
引用
收藏
页码：10149 / 10152
页数：4
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