Coinage metal complexes of BN analogues of m-terphenyl ligands

被引：1

作者：

Lamprecht, Anna ^{[1
,2
]}

Lindl, Felix ^{[1
,2
]}

Endres, Lukas ^{[1
,2
]}

Krummenacher, Ivo ^{[1
,2
]}

Braunschweig, Holger ^{[1
,2
]}

机构：

[1] Julius Maximilians Univ Wurzburg, Inst Inorgan Chem, D-97074 Wurzburg, Germany

[2] Julius Maximilians Univ Wurzburg, Inst Sustainable Chem & Catalysis Boron, D-97074 Wurzburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 67期

关键词：

COMPOUND;

D O I：

10.1039/d3cc03467d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the synthesis of a series of group 11 metal complexes with sterically demanding anionic nitrogen ligands based on the 1,2-azaborinine motif. The ligands, which share structural similarities with m-terphenyls, have been used to stabilize two-coordinate phosphine complexes and dimeric complexes with close contacts between the metal centers. Spectroscopic, crystallographic, and theoretical investigations reveal close parallels to the related m-terphenyl complexes, including metallophilic interactions in the dimers.

引用

页码：10149 / 10152

页数：4

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