Alkyl Ammonium Tungstate Bonded to Fe3O4@SiO2 Nanoparticles; a highly efficient Catalyst for the Oxidation of Symmetrical Sulfides to Symmetrical Sulfoxides

被引:4
|
作者
Khatami, Seyed-Mola [1 ]
Khalaj, Mehdi [2 ]
Ghashang, Majid [3 ]
机构
[1] Tech & Vocat Univ TVU, Dept Chem Ind, Tehran, Iran
[2] Islamic Azad Univ, Dept Chem, Buinzahra Branch, Buinzahra, Iran
[3] Islamic Azad Univ, Dept Chem, Najafabad Branch, POB 517, Najafabad, Iran
来源
IRANIAN JOURNAL OF CATALYSIS | 2023年 / 13卷 / 04期
关键词
Magnetic nano catalysis; Organic-inorganic hybrids; Oxidation; Symmetrical sulfide; Symmetrical sulfoxide; SELECTIVE OXIDATION; ENANTIOSELECTIVE ARYLATION; SULFENATE ANIONS; IONIC LIQUID; ACID; DERIVATIVES; SULFUR; MILD;
D O I
10.30495/IJC.2023.1993331.2039
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A magnetic organic-inorganic hybrid of Fe3O4@SiO2-functionalized propylpiperazine-1,4-diium tungstate (A) nanoparticles with a spherical structure was prepared and completely characterized by XRD, SEM, TGA-DTA, and FT-IR spectral techniques. The magnetic hybrid was used in the oxidation of symmetrical sulfides to symmetrical sulfoxides under ambient conditions. The excellent yields of sulfoxides, easy operation, and recovery, magnetic properties of the catalyst, and environmentally friendly system are the key advantages of this method.
引用
收藏
页码:475 / 485
页数:11
相关论文
共 50 条
  • [21] A magnetically recyclable Fe3O4@SiO2/Mn(III) chiral salen complex as a highly selective and versatile heterogeneous nanocatalyst for the oxidation of olefins and sulfides
    Allahresani, Ali
    Nasseri, Mohammad Ali
    RSC ADVANCES, 2014, 4 (105): : 60702 - 60710
  • [22] Anchored N,O-Cu complex over Fe3O4@SiO2 as a highly efficient and reusable catalyst for C-O coupling reaction
    Zahedi, Razieh
    Asadi, Zahra
    Firuzabadi, Fahimeh Dehghani
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2019, 580
  • [23] Palladium nanoparticles immobilized on EDTA-modified Fe3O4@SiO2: a highly stable and efficient magnetically recoverable catalyst for the Heck-Mizoroki coupling reactions
    Esmaeilpour, Mohsen
    Zahmatkesh, Saeed
    INORGANIC AND NANO-METAL CHEMISTRY, 2019, 49 (08) : 267 - 276
  • [24] Design, preparation and characterization of Cu/GA/Fe3O4@SiO2 nanoparticles as a catalyst for the synthesis of benzodiazepines and imidazoles
    Shaabani, Ahmad
    Sepahvand, Heshmatollah
    Hooshmand, Seyyed Emad
    Boroujeni, Mahmoud Borjian
    APPLIED ORGANOMETALLIC CHEMISTRY, 2016, 30 (06) : 414 - 421
  • [25] Nanobiomechanical behavior of Fe3O4@SiO2 and Fe3O4@SiO2-NH2 nanoparticles over HeLa cells interfaces
    Carlos Camacho-Fernandez, Juan
    Karendash Gonzalez-Quijano, Genesis
    Severac, Childerick
    Dague, Etienne
    Gigoux, Veronique
    Santoyo-Salazar, Jaime
    Martinez-Rivas, Adrian
    NANOTECHNOLOGY, 2021, 32 (38)
  • [26] Preparation and performance of magnetic microspheres encapsulating Fe3O4@SiO2 nanoparticles
    Zhang, Liyuan
    Bai, Xuewen
    Zou, Kai
    Zhu, Linlin
    JOURNAL OF CHEMICAL RESEARCH, 2024, 48 (05)
  • [27] Magnetic sedimentation and aggregation of Fe3O4@SiO2 nanoparticles in water medium
    Bakhteeva, Iu A.
    Medvedeva, I. V.
    Uimin, M. A.
    Byzov, I. V.
    Zhakov, S. V.
    Yermakov, A. E.
    Shchegoleva, N. N.
    SEPARATION AND PURIFICATION TECHNOLOGY, 2016, 159 : 35 - 42
  • [28] Fe3O4@SiO2 nanoparticles as a high-performance Fenton-like catalyst in a neutral environment
    Yang, Sheng-Tao
    Zhang, Wu
    Xie, Jingru
    Liao, Rong
    Zhang, Xiaoliang
    Yu, Baowei
    Wu, Ruihan
    Liu, Xiaoyang
    Li, Hongliang
    Guo, Zhen
    RSC ADVANCES, 2015, 5 (07): : 5458 - 5463
  • [29] Magnetic Fe3O4@SiO2 study on adsorption of methyl orange on nanoparticles
    Heng Li
    Huanhuan Jin
    Ranran Li
    Junpeng Hua
    Zhen Zhang
    Ruixin Li
    Scientific Reports, 14
  • [30] Magnetic Fe3O4@SiO2 study on adsorption of methyl orange on nanoparticles
    Li, Heng
    Jin, Huanhuan
    Li, Ranran
    Hua, Junpeng
    Zhang, Zhen
    Li, Ruixin
    SCIENTIFIC REPORTS, 2024, 14 (01)