Alkyl Ammonium Tungstate Bonded to Fe3O4@SiO2 Nanoparticles; a highly efficient Catalyst for the Oxidation of Symmetrical Sulfides to Symmetrical Sulfoxides

被引:4
|
作者
Khatami, Seyed-Mola [1 ]
Khalaj, Mehdi [2 ]
Ghashang, Majid [3 ]
机构
[1] Tech & Vocat Univ TVU, Dept Chem Ind, Tehran, Iran
[2] Islamic Azad Univ, Dept Chem, Buinzahra Branch, Buinzahra, Iran
[3] Islamic Azad Univ, Dept Chem, Najafabad Branch, POB 517, Najafabad, Iran
来源
IRANIAN JOURNAL OF CATALYSIS | 2023年 / 13卷 / 04期
关键词
Magnetic nano catalysis; Organic-inorganic hybrids; Oxidation; Symmetrical sulfide; Symmetrical sulfoxide; SELECTIVE OXIDATION; ENANTIOSELECTIVE ARYLATION; SULFENATE ANIONS; IONIC LIQUID; ACID; DERIVATIVES; SULFUR; MILD;
D O I
10.30495/IJC.2023.1993331.2039
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A magnetic organic-inorganic hybrid of Fe3O4@SiO2-functionalized propylpiperazine-1,4-diium tungstate (A) nanoparticles with a spherical structure was prepared and completely characterized by XRD, SEM, TGA-DTA, and FT-IR spectral techniques. The magnetic hybrid was used in the oxidation of symmetrical sulfides to symmetrical sulfoxides under ambient conditions. The excellent yields of sulfoxides, easy operation, and recovery, magnetic properties of the catalyst, and environmentally friendly system are the key advantages of this method.
引用
收藏
页码:475 / 485
页数:11
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