ADDP facilitates C-S bond formation from sulfonyl chlorides with alcohols

被引：2
|
作者：
Sun, Gang [1 ]
Liu, Xin [1 ]
Li, Jing [1 ]
Yang, Jian-Xin [1 ]
Xie, Jun-Kai [1 ]
Wen, Xiaoan [1 ]
Sun, Hongbin [1 ]
Xu, Qing-Long [1 ]
机构：
[1] China Pharmaceut Univ, Jiangsu Key Lab Drug Discovery Metab Dis, State Key Lab Nat Med, 24 Tongjia Xiang, Nanjing 210009, Peoples R China
来源：
NEW JOURNAL OF CHEMISTRY | 2023年 / 47卷 / 10期
基金：
中国国家自然科学基金;
关键词：
ONE-POT SYNTHESIS; CATALYZED ODORLESS SYNTHESIS; CROSS-COUPLING REACTION; ARYL HALIDES; MITSUNOBU REACTIONS; SULFUR; SULFIDES; DEOXYGENATION; THIOETHERS; THIOLS;
D O I：
10.1039/d2nj06287a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The formation of C-S bonds using cheap, stable and odorless sulfonyl chlorides and widely sourced and less toxic alcohols with the assistance of ADDP is reported. This method is suitable for a broad substrate scope and tolerates a broad range of functional groups. Additionally, our protocol provides a green and convenient methylating method utilizing methanol or methanol-d(4) and allows trideuteromethylthiolation with sulfonyl chlorides. This method can be applied for the late-stage diversification of natural products and drug analogs.
引用
收藏
页码：4746 / 4751
页数：6
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