Dioxygen-triggered oxidative cleavage of the C-S bond towards C-N bond formation

被引：9

作者：

Lv, Zongchao ^{[1
]}

Wang, Huamin ^{[1
]}

Quan, Zhicong ^{[1
]}

Gao, Yuan ^{[1
]}

Lei, Aiwen ^{[1
,2
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Inst Adv Studies, Wuhan 430072, Hubei, Peoples R China

[2] Jiangxi Normal Univ, Natl Res Ctr Carbohydrate Synth, Nanchang 330022, Jiangxi, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 82期

基金：

中国国家自然科学基金;

关键词：

PALLADIUM-CATALYZED AMINATION; CARBON-SULFUR; COOPERATIVE CATALYSIS; EFFICIENT SYNTHESIS; METAL-COMPLEXES; ACTIVATION; FUNCTIONALIZATION; COBALT; BENZOXAZOLES; CYCLIZATION;

D O I：

10.1039/c9cc05707b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Research on the cleavage of C-C bonds has been well developed. By comparison with this, the activation of C-S bonds remains challenging. Herein, dioxygen-triggered oxidative cleavage of C-S bonds has been achieved, delivering a series of N-containing heterocyclic compounds that are frequently found in pesticides and pharmaceuticals. Additionally, the potential utility of this protocol was further demonstrated by a gram-scale experiment. Mechanistically, dioxygen plays a key role in the cleavage of C-S bonds towards C-N bond formation.

引用

页码：12332 / 12335

页数：4

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