Vinylene Carbonate as Synthon in Transition Metal-Catalyzed C-H Bond Activation/Annulation Reactions

被引：12
|
作者：
Cui, Xiaofan [1 ,2 ]
Chauvin, Remi [1 ,2 ,3 ]
Pi, Chao [1 ,2 ]
Wu, Yangjie [1 ,2 ]
Cui, Xiuling [1 ,2 ]
机构：
[1] Zhengzhou Univ, Green Catalysis Ctr, Key Lab Appl Chem Henan Univ, Henan Key Lab Chem Biol & Organ Chem, Zhengzhou 450052, Peoples R China
[2] Zhengzhou Univ, Coll Chem, Zhengzhou 450052, Peoples R China
[3] Univ Toulouse, LCC, Toulouse 3 Paul Sabatier, 205 Route Narbonne, F-31077 Toulouse, France
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2023年 / 365卷 / 20期
关键词：
C-H bond activation; Vinylene carbonate; Transition-metal-catalysis; Heterocycles; ANNULATION; AROMATICITY; CYCLIZATION;
D O I：
10.1002/adsc.202300601
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Recently, vinylene carbonate has been developed as a powerful synthon in transition metal-catalyzed C-H bond activation/cyclization reactions. This review introduces recent progress in the use of vinylene carbonate as a reactant, by analyzing and comparing reaction models involving vinylene carbonate as a surrogate of ethynol, acetylene, acetylation reagents or other reactants, while addressing related mechanisms and synthetic applications. image
引用
收藏
页码：3400 / 3412
页数：13
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