Metal-Catalyzed/Mediated Aromatic C-H Bond Trifluoromethylation

被引:2
|
作者
Kamei, Toshiyuki
机构
关键词
PERFLUOROALKANESULFONYL CHLORIDES; ARENES; COMPLEX; PERFLUOROALKYLATION; HETEROARENES; CATALYSIS;
D O I
10.5059/yukigoseikyokaishi.70.756
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Trifluoromethyl group is one of the important groups in medicinal chemistry. In 2010, Yu and Sanford reported the Pd-catalyzed aromatic C-H bond trifluoromethylation with the aid of directing groups. With these reports as a turning point, the studies on this field have been developed in a couple of years. This review describes the recent advances in aromatic C-H bond trifluoromethylation catalyzed/mediated by transition metal reagents.
引用
收藏
页码:756 / 757
页数:2
相关论文
共 50 条
  • [1] Transition Metal-Catalyzed C-H Trifluoromethylation
    Pan Fei
    Shi Zhangjie
    ACTA CHIMICA SINICA, 2012, 70 (16) : 1679 - 1681
  • [2] Metal-Catalyzed C-H Bond Functionalization
    Baudoin, Olivier
    TETRAHEDRON, 2013, 69 (22) : 4370 - 4370
  • [3] Metal-catalyzed C-H bond functionalization of phenol derivatives
    Al Mamari, Hamad H.
    Stefane, Bogdan
    Zugelj, Helena Brodnik
    TETRAHEDRON, 2020, 76 (09)
  • [4] Towards mild metal-catalyzed C-H bond activation
    Wencel-Delord, Joanna
    Droege, Thomas
    Liu, Fan
    Glorius, Frank
    CHEMICAL SOCIETY REVIEWS, 2011, 40 (09) : 4740 - 4761
  • [5] Palladium-Catalyzed Trifluoromethylation of Aromatic C-H Bond Directed by an Acetamino Group
    Zhang, Li-Sheng
    Chen, Kang
    Chen, Guihua
    Li, Bi-Jie
    Luo, Shuang
    Guo, Qing-Yun
    Wei, Jiang-Bo
    Shi, Zhang-Jie
    ORGANIC LETTERS, 2013, 15 (01) : 10 - 13
  • [6] Synthesis of rhazinicine by a metal-catalyzed C-H bond functionalization strategy
    Beck, Elizabeth M.
    Hatley, Richard
    Gaunt, Matthew J.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) : 3004 - 3007
  • [7] Transition Metal-Catalyzed Regio-selective Aromatic C-H Bond Oxidation for C-O Bond Formation
    Yang, Fanzhi
    Zhang, Han
    Liu, Xuri
    Wang, Bo
    Lutz, Ackermann
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2019, 39 (01) : 59 - 73
  • [8] Metal-catalyzed functionalization of sp3 C-H bond
    Yun, Sang Young
    Wang, Kung-Pern
    Mamidipalli, Phani
    Lee, Nam-Kyu
    Lee, Daesung
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [9] Exploiting the C-H bond in metal-catalyzed C-C bond-forming reactions
    Schnuerch, Michael
    ARKIVOC, 2015, : 212 - 243
  • [10] Copper-catalyzed/mediated aromatic C-H bond functionalization
    Zhang, Ming
    APPLIED ORGANOMETALLIC CHEMISTRY, 2010, 24 (04) : 269 - 284