Crystal structure of 2-methyl-1H-imidazol-3-ium 3,5-dicarboxybenzoate

被引：1
|
作者：
Baletska, Sofiia [1 ]
Techert, Simone [2 ,3 ]
Velazquez-Garcia, Jose de Jesus [2 ]
机构：
[1] Kharkov Natl Univ, Sch Phys, 4 Svobody Sq, UA-61022 Kharkiv, Ukraine
[2] Deutsch Elektronen Synchrotron DESY, Notkestr 85, D-22607 Hamburg, Germany
[3] Georg August Univ Gottingen, Inst Ronthenphys, Friedrich Hund Pl 1, D-37077 Gottingen, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷
关键词：
crystal structure; 2-methylimidazole; trimesic acid; TRIMESIC ACID; DERIVATIVES; COMPLEXES; NETWORKS; SOLVATE;
D O I：
10.1107/S2056989023009209
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structure of the title salt, C4H7N2+center dot C9H5O6- (1), is reported. The compound is built from a protonated 2-methylimidazole and a singly deprotonated trimesic acid. Detailed analysis of bond distances and angles for both ions reveals subtle differences compared with their neutral molecule counterpart. Analysis of the crystal packing in compound 1 reveals the formation of undulating chains by the ions through hydrogen bonding. The chains stack along the b axis through pi-pi interactions and interconnect with other chains in an out-of-phase arrangement along the ac plane through further hydrogen-bonding interactions.
引用
收藏
页码：1088 / +
页数：10
相关论文
共 50 条
  • [31] 1-(6-bromopyridin-2-yl)-3-methyl-3H-imidazol-1-ium bromide monohydrate
    Cheng, PY
    Zeng, JY
    Chiu, PL
    Lee, HM
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O509 - O510
  • [32] Crystal structure of 1,1′-butanebis(3-methyl-1H-imidazol-3-ium)bis(hexafluorophosphate), C12H20F12N4P2
    Xiong Wan-Ming
    Jing, Chen
    Peng Da-Yong
    Nie Xu-Liang
    Huang, Chang-gan
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2017, 232 (06): : 1007 - 1008
  • [33] Crystal structure of 2-ethyl-4-methyl-1-(2-oxido-3,4-dioxocyclobut-1-en-1-yl)-1H-imidazol-3-ium
    Korkmaz, Ufuk
    Bulut, Iclal
    Bulut, Ahmet
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 998 - +
  • [34] Crystal structure of bis[1-{(3,5-dimethyl-1H-pyrazol-1-yl)methyl}-3,5-dimethyl-1H-pyrazol-2-ium] hexachlorouranate(IV): [H2C(3,5-Me2pz)(3,5-Me2pzH)]2[UCl6]
    J. M. Carretas
    J. Cui
    A. Cruz
    I. C. Santos
    J. Marçalo
    Journal of Structural Chemistry, 2015, 56 : 181 - 185
  • [35] Crystal structure of bis[1-{(3,5-dimethyl-1H-pyrazol-1-yl)methyl}-3,5-dimethyl-1H-pyrazol-2-ium] hexachlorouranate(IV): [H2C(3,5-Me2pz)(3,5-Me2pzH)]2[UCl6]
    Carretas, J. M.
    Cui, J.
    Cruz, A.
    Santos, I. C.
    Marcalo, J.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 56 (01) : 181 - 185
  • [36] 2-Phenyl-1H-imidazol-3-ium hydrogen oxalate
    Song, Jin-Na
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1773 - U1406
  • [37] 1H-Imidazol-3-ium-4-carboxylate
    Cao, Qiang
    Duan, Bao-Rong
    Zhu, Bin
    Cao, Zhen
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68
  • [38] Crystal structure of 1,3-dicyclohexyl-4,5-dimethyl-1H-imidazol-3-ium-2-carbodithioate chloroform monosolvate
    Mallah, Eyad
    Sweidan, Kamal
    Abu Dayyih, Wael
    Steimann, Manfred
    Sunjuk, Mahmoud
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O1227 - +
  • [39] The crystal structure of 1-(4-carboxybutyl)-3-methyl-1H-imidazol-3-ium hexafluoridophosphate, C9H15F6N2O2P
    Mao, Zhiwei
    Zhang, Kehua
    Zhou, Lian
    Zou, Wensheng
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2024, 239 (03): : 561 - 563
  • [40] Crystal structure of 2-(1H-imidazol-3-ium-4-yl)ethanaminium dichloride, a re-determination
    Louhibi, Samira
    Belfilali, Imene
    Boukli-Hacene, Leila
    Roisnel, Thierry
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O844 - U411
12345