Crystal structure of 2-methyl-1H-imidazol-3-ium 3,5-dicarboxybenzoate

被引：1
|
作者：
Baletska, Sofiia [1 ]
Techert, Simone [2 ,3 ]
Velazquez-Garcia, Jose de Jesus [2 ]
机构：
[1] Kharkov Natl Univ, Sch Phys, 4 Svobody Sq, UA-61022 Kharkiv, Ukraine
[2] Deutsch Elektronen Synchrotron DESY, Notkestr 85, D-22607 Hamburg, Germany
[3] Georg August Univ Gottingen, Inst Ronthenphys, Friedrich Hund Pl 1, D-37077 Gottingen, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷
关键词：
crystal structure; 2-methylimidazole; trimesic acid; TRIMESIC ACID; DERIVATIVES; COMPLEXES; NETWORKS; SOLVATE;
D O I：
10.1107/S2056989023009209
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structure of the title salt, C4H7N2+center dot C9H5O6- (1), is reported. The compound is built from a protonated 2-methylimidazole and a singly deprotonated trimesic acid. Detailed analysis of bond distances and angles for both ions reveals subtle differences compared with their neutral molecule counterpart. Analysis of the crystal packing in compound 1 reveals the formation of undulating chains by the ions through hydrogen bonding. The chains stack along the b axis through pi-pi interactions and interconnect with other chains in an out-of-phase arrangement along the ac plane through further hydrogen-bonding interactions.
引用
收藏
页码：1088 / +
页数：10
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