Ultrasound-Assisted Synthesis of C60 Fullerene-Fused 1,4-Oxathian-2-ones

被引：0

作者：

Kinzyabaeva, Z. S. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochem & Catalysis, Ufa 450075, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2023年 / 93卷 / SUPPL 1期

关键词：

C-60; fullerene; mercaptocarboxylic acids; 1,4-oxathian-2-one; 4+2]-cycloaddition; ultrasound; sonochemistry; SONOCHEMICAL SYNTHESIS; OXIDATION; CHEMISTRY; EPOXIDE; WATER; ACID;

D O I：

10.1134/S1070363223140219

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Previously unknown C-60 fullerene-fused 1,4-oxathian-2-ones 1,9-[2 '-oxo-1 ',4 '-oxathiano]-1,9-dihydro-(C-60-I-h)[5,6]fullerene and 1,9-[3 '-Methyl-2 '-oxo-1 ',4 '-oxathiano]-1,9-dihydro-(C-60-I-h)[5,6]fullerene were obtained by a selective reaction mercaptocarboxylic acids (mercaptoacetic and 2-mercaptopropionic) with fullerene epoxide C60O in the presence of NaOH in an inert atmosphere at room temperature under ultrasonication for 1 h. The yields of the target product were estimated at 96 and 87%, respectively (by HPLC). A plausible reaction mechanism for was proposed.

引用

页码：S131 / S136

页数：6

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