Reactivity and mechanism of the action of C60 fullerene used as an inhibitor for the radical chain oxidation of 1,4-dioxane

被引：0
|
作者：
A. Ya. Gerchikov
G. M. Sharipova
I. V. Safarova
M. V. Sakhibgareeva
S. I. Spivak
机构：
[1] Bashkir State University,
[2] OOO RN-UfaNIOIneft,undefined
来源：
Russian Journal of Physical Chemistry A | 2017年 / 91卷
关键词：
1,4-dioxane; rate constant; kinetics; radicals; oxidation; fullerene; mathematical model;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The kinetics and mechanism of the antioxidative action of С60 fullerene are studied via highly sensitive manometry and kinetic spectrophotometry, based on the example of a model reaction of the initiated oxidation of 1,4-dioxane. The adequacy of the proposed mechanism according to the experimental data is analyzed by means of mathematical modeling. The mechanism behind the inhibiting process is found to be a multi-center radical reaction. The rate constants of the elementary stages are determined.
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页码：1010 / 1014
页数：4
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