Regioselective synthesis of β-hydroxy sulfides using aryl halides

被引：1

作者：

Nowrouzi, Najmeh ^{[1
]}

Abbasi, Mohammad ^{[1
]}

Shahidzadeh, Elham Shaikhi ^{[1
]}

机构：

[1] Persian Gulf Univ, Fac Nano & Bio Sci & Technol, Dept Chem, Bushehr 75169, Iran

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2023年 / 37卷 / 02期

关键词：

aryl halides; cyanodithioformate; diaryl disulfide; styrene; beta-hydroxy sulfides; ONE-POT SYNTHESIS; HYDROXYSULFENYLATION; SULFOXIDES; STYRENES; ALKENES; SULFUR; DERIVATIVES; THIOLYSIS; DIFUNCTIONALIZATION; DISULFIDES;

D O I：

10.1002/aoc.6941

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Cyanodithioformate salt as an odorless and simply operational source of sulfur was reacted with aryl halides in the presence of copper iodide, affording diaryl disulfide, which reacted with styrenes/alpha-methylstyrene in second step to form beta-Hydroxy sulfides with high regioselectivity in good to excellent yields.

引用

页数：9

共 50 条

[41] Palladium-catalyzed synthesis of aryl sulfides from aryl triflates
Zheng, N
McWilliams, JC
Fleitz, FJ
Armstrong, JD
Volante, RP
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (26): : 9606 - 9607
[42] REGIOSELECTIVE SYNTHESIS OF ALLYL TRIMETHYLSILANES FROM ALLYLIC HALIDES
SMITH, JG
QUINN, NR
VISWANATHAN, M
SYNTHETIC COMMUNICATIONS, 1983, 13 (09) : 773 - 779
[43] Temperature dependent regioselective synthesis of aryl tetrazole amines using copper source
Boddapati, S. N. Murthy
Kola, A. Emmanuel
Kesana, Surendra Babu
Bollikolla, Hari Babu
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 866 : 177 - 183
[44] Reduction of aryl thiocyanates with SmI2 and Pd-catalyzed coupling with aryl halides as a route to mixed aryl sulfides
Still, IWJ
Toste, FD
JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (22): : 7677 - 7680
[45] REACTIONS OF ARYL HALIDES WITH THIOLATE ANIONS IN PRESENCE OF CATALYTIC AMOUNTS OF TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM PREPARATION OF ARYL SULFIDES
KOSUGI, M
SHIMIZU, T
MIGITA, T
CHEMISTRY LETTERS, 1978, (01) : 13 - 14
[46] SYNTHESIS OF ARYL HALIDES VIA ORGANOBORANE CHEMISTRY
KABALKA, GW
SASTRY, KAR
SASTRY, U
SOMAYAJI, V
ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1982, 14 (05) : 359 - 362
[47] Synthesis of α-Arylated Esters from Aryl Halides
Wei DENG
Chinese Chemical Letters, 2006, (05) : 595 - 598
[48] Synthesis of α-arylated esters from aryl halides
Deng, Wei
Wang, Ye Feng
Liu, Lei
Guo, Qing Xiang
CHINESE CHEMICAL LETTERS, 2006, 17 (05) : 595 - 598
[49] REGIOSELECTIVE SYNTHESIS OF HYDROXY BUTENOLIDES - A CONVENIENT SYNTHESIS OF A-FACTOR
YADAV, JS
MURALIKRISHNA, V
RAO, AVR
TETRAHEDRON LETTERS, 1994, 35 (21) : 3609 - 3612
[50] MONTMORILLONITE CLAY-CATALYZED REGIOSELECTIVE RING-OPENING OF OXIRANES WITH THIOPHENOL - A SIMPLE SYNTHESIS OF BETA-HYDROXY SULFIDES
MAITI, AK
BISWAS, GK
BHATTACHARYYA, P
JOURNAL OF CHEMICAL RESEARCH-S, 1993, (08): : 325 - 325

← 1 2 3 4 5 →