Regioselective synthesis of β-hydroxy sulfides using aryl halides

被引：1
|
作者：
Nowrouzi, Najmeh [1 ]
Abbasi, Mohammad [1 ]
Shahidzadeh, Elham Shaikhi [1 ]
机构：
[1] Persian Gulf Univ, Fac Nano & Bio Sci & Technol, Dept Chem, Bushehr 75169, Iran
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2023年 / 37卷 / 02期
关键词：
aryl halides; cyanodithioformate; diaryl disulfide; styrene; beta-hydroxy sulfides; ONE-POT SYNTHESIS; HYDROXYSULFENYLATION; SULFOXIDES; STYRENES; ALKENES; SULFUR; DERIVATIVES; THIOLYSIS; DIFUNCTIONALIZATION; DISULFIDES;
D O I：
10.1002/aoc.6941
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Cyanodithioformate salt as an odorless and simply operational source of sulfur was reacted with aryl halides in the presence of copper iodide, affording diaryl disulfide, which reacted with styrenes/alpha-methylstyrene in second step to form beta-Hydroxy sulfides with high regioselectivity in good to excellent yields.
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页数：9
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