A zirconium-based metal-organic framework with dibenzothiophene linkers: synthesis, structural analysis, and gas-adsorption properties

被引：4

作者：

Sugamata, Koh ^{[1
,3
]}

Kobayashi, Sho ^{[1
]}

Amanokura, Natsuki ^{[1
,2
]}

Shirai, Akihiro ^{[1
,2
]}

Minoura, Mao ^{[1
,3
]}

机构：

[1] Rikkyo Univ, Coll Sci, Dept Chem, Toshima, Japan

[2] Nippon Soda Co Ltd, Chiyoda Ku, Tokyo, Japan

[3] Rikkyo Univ, Coll Sci, Dept Chem, Toshima 1718501, Japan

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2023年 / 76卷 / 16-24期

关键词：

Metal-organic frameworks (MOFs); coordination polymers; gas-adsorption properties; x-ray diffraction analysis; COORDINATION POLYMERS; METHANE; CO2; MOFS; CH4; SELECTIVITY; HKUST-1; STORAGE; DESIGN; N-2;

D O I：

10.1080/00958972.2023.2287970

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A UiO-67-type Zr-based metal-organic framework (MOF) with dibenzothiophene linkers, UiO-67-S, was synthesized using a solvothermal method. The crystal structure of UiO-67-S exhibits the same topological structure as UiO-67 and its derivatives. UiO-67-S shows high thermal stability and excellent permanent porosity. Moreover, its excellent hydrogen storage indicates that the thiophene moiety is suitable for enhancing the hydrogen storage ability of MOFs.

引用

页码：1817 / 1824

页数：8

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