A zirconium-based metal-organic framework with dibenzothiophene linkers: synthesis, structural analysis, and gas-adsorption properties

被引：4

作者：

Sugamata, Koh ^{[1
,3
]}

Kobayashi, Sho ^{[1
]}

Amanokura, Natsuki ^{[1
,2
]}

Shirai, Akihiro ^{[1
,2
]}

Minoura, Mao ^{[1
,3
]}

机构：

[1] Rikkyo Univ, Coll Sci, Dept Chem, Toshima, Japan

[2] Nippon Soda Co Ltd, Chiyoda Ku, Tokyo, Japan

[3] Rikkyo Univ, Coll Sci, Dept Chem, Toshima 1718501, Japan

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2023年 / 76卷 / 16-24期

关键词：

Metal-organic frameworks (MOFs); coordination polymers; gas-adsorption properties; x-ray diffraction analysis; COORDINATION POLYMERS; METHANE; CO2; MOFS; CH4; SELECTIVITY; HKUST-1; STORAGE; DESIGN; N-2;

D O I：

10.1080/00958972.2023.2287970

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A UiO-67-type Zr-based metal-organic framework (MOF) with dibenzothiophene linkers, UiO-67-S, was synthesized using a solvothermal method. The crystal structure of UiO-67-S exhibits the same topological structure as UiO-67 and its derivatives. UiO-67-S shows high thermal stability and excellent permanent porosity. Moreover, its excellent hydrogen storage indicates that the thiophene moiety is suitable for enhancing the hydrogen storage ability of MOFs.

引用

页码：1817 / 1824

页数：8

共 50 条

[21] Imparting Multifunctionality by Utilizing Biporosity in a Zirconium-Based Metal-Organic Framework
Jadhav, Ashwini
Gupta, Kriti
Ninawe, Pranay
Ballav, Nirmalya
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (06) : 2215 - 2219
[22] Activation of Methyltrioxorhenium for Olefin Metathesis in a Zirconium-Based Metal-Organic Framework
Korzynski, Maciej D.
Consoli, Daniel F.
Zhang, Shiran
Roman-Leshkov, Yuriy
Dinca, Mircea
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (22) : 6956 - 6960
[23] Contributions of metalloporphyrin linkers and Zr6 nodes in gas adsorption on a series of bioinspired zirconium-based metal-organic frameworks: A computational study
Oveisi, Ali Reza
Delarami, Hojat Samareh
Khajeh, Mostafa
Mirjahanshahi, Sedigheh
Haghani, Abdolhossein
Daliran, Saba
Ghaffari-Moghaddam, Mansour
JOURNAL OF MOLECULAR STRUCTURE, 2020, 1204
[24] Function-oriented synthesis of zirconium-based metal-organic framework with a novel topology for efficient flue gas desulfurization
Li, Jianyun
Shi, Guanyu
Shi, Zhaohui
Feng, Binyao
Li, Wen
Li, Guanghua
Zhang, Lirong
Liu, Xin
Liu, Yunling
CHEMICAL ENGINEERING JOURNAL, 2025, 509
[25] Functionalization of zirconium-based metal-organic frameworks for gas sensing applications
Lee, Jae-Hyoung
Trang Thi Thu Nguyen
Linh Ho Thuy Nguyen
Thang Bach Phan
Sang Sub Kim
Tan Le Hoang Doan
JOURNAL OF HAZARDOUS MATERIALS, 2021, 403
[26] Dye adsorption of aluminium- and zirconium-based metal organic frameworks with azobenzene dicarboxylate linkers
Mogale, Refilwe
Akpomie, Kovo G.
Conradie, Jeanet
Langner, Ernst H. G.
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2022, 304
[27] Application of Self-Adhesive Zirconium-Based Metal-Organic Framework Materials in Dichromate Ions Adsorption
Yu F.
Zhang X.
Zhu H.
Yu B.
Guo Y.
Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2021, 37 (01): : 88 - 94
[28] Predicting the adsorption capacity of organic dye using zirconium-based metal-organic framework: a comparative analysis of RSM and ANN-based models
Dahlan, Irvan
Obi, Christopher Chiedozie
Poopathi, Veshmen
BIOMASS CONVERSION AND BIOREFINERY, 2025, 15 (01) : 285 - 295
[29] Insights on selective Ag plus adsorption in zirconium-based metal-organic frameworks: Morphology and structural regulation
Li, Gan
Wang, Ting
Guo, Pengtao
Xue, Bo
Liu, Dahuan
SEPARATION AND PURIFICATION TECHNOLOGY, 2025, 364
[30] Experimental and computational investigations of zirconium-based metal-organic frameworks for bilirubin adsorption
Gan, Na
Li, Yilin
Liu, Peiran
Pang, Jingtao
Chen, Lijuan
Geng, Fang
Li, Hui
Wu, Di
MICROPOROUS AND MESOPOROUS MATERIALS, 2024, 369

← 1 2 3 4 5 →