The [μ-1,2-Bis(dipheylphosphino)ethane-κ2P,P']bis(3-mercapto-1,2-propanediolato-κS-gold(I))

被引：0
|
作者：
Baba, Taichi [1 ]
Yoshinari, Nobuto [1 ]
机构：
[1] Osaka Univ, Grad Sch Sci, Dept Chem, Osaka 5600043, Japan
来源：
MOLBANK | 2023年 / 2023卷 / 03期
关键词：
gold complex; phosphines; thioglycerol; aurophilic interaction; PHOTOPHYSICAL PROPERTIES; CRYSTAL-STRUCTURE; STRUCTURAL-CHARACTERIZATION; GOLD(I); COMPLEXES; SERIES; EXCHANGE; LIGAND; METALLOLIGANDS; LUMINESCENCE;
D O I：
10.3390/M1698
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new dinuclear gold(I) complex, possessing a bridging diphosphine ligand (1,2-bis(diphenylphosphino)ethane) and two terminal thiol ligands (1-thioglycerol), was synthesized and fully characterized by IR, 1H and 31P NMR, fluorescence, ESI-mass, and diffuse reflection spectroscopy, together with X-ray diffraction and elemental analyses. The compound formed a 1D chain supramolecular structure through intermolecular aurophilic interactions in the crystal structure, leading to photoluminescence in the solid state.
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页数：7
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