The [μ-1,2-Bis(dipheylphosphino)ethane-κ2P,P']bis(3-mercapto-1,2-propanediolato-κS-gold(I))

被引：0
|
作者：
Baba, Taichi [1 ]
Yoshinari, Nobuto [1 ]
机构：
[1] Osaka Univ, Grad Sch Sci, Dept Chem, Osaka 5600043, Japan
来源：
MOLBANK | 2023年 / 2023卷 / 03期
关键词：
gold complex; phosphines; thioglycerol; aurophilic interaction; PHOTOPHYSICAL PROPERTIES; CRYSTAL-STRUCTURE; STRUCTURAL-CHARACTERIZATION; GOLD(I); COMPLEXES; SERIES; EXCHANGE; LIGAND; METALLOLIGANDS; LUMINESCENCE;
D O I：
10.3390/M1698
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new dinuclear gold(I) complex, possessing a bridging diphosphine ligand (1,2-bis(diphenylphosphino)ethane) and two terminal thiol ligands (1-thioglycerol), was synthesized and fully characterized by IR, 1H and 31P NMR, fluorescence, ESI-mass, and diffuse reflection spectroscopy, together with X-ray diffraction and elemental analyses. The compound formed a 1D chain supramolecular structure through intermolecular aurophilic interactions in the crystal structure, leading to photoluminescence in the solid state.
引用
收藏
页数：7
相关论文
共 50 条
  • [21] [μ-1,2-Bis(diphenylphosphanyl)-1,2-diethylhydrazine-κ2P:P′]bis[chloridogold(I)] tetrahydrofuran disolvate
    Kriel, Frederik H.
    Fernandes, Manuel A.
    Coates, Judy
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M155 - U453
  • [22] [μ-1,2-bis(phenylsulfanyl)ethane-κ2S:S′]-bis[dibromomercury(II)]
    Gong, JB
    Zhou, LN
    Chen, W
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M440 - M441
  • [23] Acetonitrile-κN){1,2-bis[bis(pentafluorophenyl)-phosphino}ethane-κ2P,P}(η5-pentamethylcyclopentadienyl)ruthenium(II) hexafluorophosphate
    Bellabarba, RM
    Nieuwenhuyzen, M
    Saunders, GC
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M1588 - M1589
  • [24] catena-Poly[[(nitrato-κ2O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ2P:P′]
    Wang, Xing-Cong
    Wu, Yan-Li
    You, Xiu-Li
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M981 - U106
  • [25] [1,2-Bis(diphenylphosphino)ethane-κ2P,P′](2-carboxylatothiophenolato-κ2O,S)nickel(II) methanol solvate
    Miao, Jinling
    Li, Furong
    Chen, Haiyan
    Wang, Daqi
    Nie, Yong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M156 - U415
  • [26] 1,2-bis(p-nitrophenoxy)ethane
    Butt, M. Saeed
    Rauf, M. Khawar
    Bolte, Michael
    Akhter, Zareen
    Zafar-uz-Zaman, M.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : O3440 - O3442
  • [27] [1,2-Bis(methylthio)ethane-κ2S,S′]dichlorozinc(II)
    Parvez, M
    Clark, PD
    Yao, H
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M313 - M314
  • [28] {μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-dimethylhydrazine-κ2P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate
    Kriel, Frederik H.
    Fernandes, Manuel A.
    Coates, Judy
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1163 - U1438
  • [29] {μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-diethylhydrazine-κ2P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate
    Kriel, Frederik H.
    Fernandes, Manuel A.
    Coates, Judy
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1426 - U1178
  • [30] [1,2-Bis(diisopropylphosphanyl)ethane-κ2 P,P′]dichloridonickel(II)-9H-carbazole (1/2)
    Canavera-Buelvas, Farah
    Flores-Alamo, Marcos
    Garcia, Juventino J.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M501 - U1024
12345