Base-mediated one-pot synthesis of alkynylsilanes from terminal alkynes and chlorosilanes

被引：1

作者：

Chen, Jianyang ^{[1
]}

Fu, Hongmei ^{[1
]}

He, Huamei ^{[1
]}

Liang, Shuting ^{[1
]}

Luo, Xiaofeng ^{[1
]}

机构：

[1] Chongqing Univ Arts & Sci, Chongqing Key Lab Resource Utilizat Heavy Met Wast, Yongchuan 402160, Peoples R China

来源：

TETRAHEDRON | 2024年 / 152卷

关键词：

One-pot method; Alkynylsilanes; Terminal alkynes; Chlorosilanes; LiN(SiMe3)2; DEHYDROGENATIVE SILYLATION; COUPLING REACTIONS; EFFICIENT; ZINC; 1-ALKYNES; ROUTE; TRIMETHYLSILYLATION; HYDROSILANES; DERIVATIVES; ACTIVATION;

D O I：

10.1016/j.tet.2024.133823

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient one -pot method has been developed to synthesize alkynylsilanes from terminal alkynes by treatment with chlorosilanes and LiN(SiMe3)2. The reaction proceeded smoothly at room temperature, showing a broad substrate scope and good functional group tolerance. The practical application was demonstrated by gram-scale reaction.

引用

页数：6

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