"2+1B" Tricarbonyl Complexes of Technetium-99m and Rhenium with N,N '-Bidentate Ligands and Methyl 2-(Decylthio)-6-isocyanohexanoate

被引：2
|
作者：
Miroslavov, A. E. [1 ,2 ,3 ]
Kuz'min, V. V. [4 ]
Sakhonenkova, A. P. [1 ,2 ,3 ]
Tyupina, M. Yu. [1 ,3 ]
Sidorenko, G. V. [1 ,3 ]
Kochergina, A. R. [1 ,3 ]
Polukeev, V. A. [4 ]
机构：
[1] Khlopin Radium Inst, St Petersburg 194021, Russia
[2] St Petersburg State Univ, St Petersburg 199034, Russia
[3] Natl Res Nucl Univ MEPhI, Ozersk Inst Technol, Branch, Ozersk 456783, Chelyabinsk Obl, Russia
[4] AO Vekton, St Petersburg 192019, Russia
来源：
RADIOCHEMISTRY | 2023年 / 65卷 / 06期
基金：
俄罗斯科学基金会;
关键词：
technetium; rhenium; tricarbonyl complexes; bipyridine; phenanthroline; methyl 2-(decylthio)-6-isocyanohexanoate; lipophilicity; FATTY-ACID-METABOLISM; MYOCARDIAL-METABOLISM; N; N'-BIDENTATE LIGANDS; BETA-OXIDATION; BIODISTRIBUTION; TECHNETIUM; VALIDATION;
D O I：
10.1134/S1066362223060085
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
"2+1(B)" tricarbonyl complexes of the general formula [M(CO)(3)(N<^>N)CN(CH2)(4)CH(COOMe)SC10H21]-ClO4, where M = Tc-99m or Re, N<^>N = 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [M(CO)(3)(N<^>N)(MeOH)]ClO4 with methyl 2-(decylthio)-6-isocyanohexanoate in methanol. The rhenium complexes were isolated and characterized by H-1 NMR and IR spectroscopy. The formation of technetium-99m complexes was confirmed by HPLC. The lipophilicity of the technetium complexes was measured.
引用
收藏
页码：672 / 679
页数：8
相关论文
共 50 条
  • [21] Technetium-99m complex of N-(2-pyridylmethyl)iminodiacetic acid as a new renal radiopharmaceutical
    Karube, Y
    Iwamoto, K
    Takata, J
    ANNALS OF NUCLEAR MEDICINE, 1999, 13 (02) : 127 - 132
  • [22] Rhenium-188 and technetium-99m nitridobis(N-ethoxy-N-ethyldithiocarbamate) leucocyte labelling radiopharmaceuticals: [Re-188;N(NOET)(2)] and [Tc-99m;N(NOET)(2)], NOET=Et(EtO)NCS2: Their in vitro localization and chemical behaviour
    Demaimay, F
    Dazord, L
    Roucoux, A
    Noiret, N
    Patin, H
    Moisan, A
    NUCLEAR MEDICINE AND BIOLOGY, 1997, 24 (08): : 701 - 705
  • [23] Absence of dichroism in dinuclear rhenium complexes with sterically hindered μ2-(η2-N,O)-nitrosobenzene ligands
    Krinninger, C
    Wirth, S
    Klüfers, P
    Mayer, P
    Lorenz, IP
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (05) : 1060 - 1066
  • [24] NEUTRAL TECHNETIUM(V) AND RHENIUM(V) COMPLEXES WITH TETRADENTATE LIGANDS CONTAINING N2OS DONOR SETS
    LIN, CH
    HUANG, ST
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1995, 25 (08): : 1219 - 1237
  • [25] Rhenium and technetium tricarbonyl complexes anchored by 5-HT1A receptor-binding ligands containing P,O/N donor atom sets
    Palma, E
    Correia, JDG
    Domingos, A
    Santos, I
    Alberto, R
    Spies, H
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (25) : 4811 - 4819
  • [26] Complexes of group 1 salts with N,N′-aromatic bidentate ligands, of mononuclear ('molecular') 1:2 salt:: Base ratio
    Buttery, Jarrod H. N.
    Effendy
    Koutsantonis, George A.
    Mutrofin, Siti
    Plackett, Neil C.
    Skelton, Brian W.
    Whitaker, Claire R.
    White, Allan H.
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (10-11): : 1829 - 1838
  • [27] NOVEL TC-99M COMPLEXES BASED ON NEW N2S2 AND N2SO LIGANDS
    OYA, S
    GUO, YZ
    KUNG, MP
    ROMANIELLO, G
    GARNER, S
    KUNG, HF
    JOURNAL OF NUCLEAR MEDICINE, 1993, 34 (05) : P135 - P135
  • [28] Red emitting [Ir(C^N)2(N^N)]+ complexes employing bidentate 2,2′:6′,2′′-terpyridine ligands for light-emitting electrochemical cells
    Constable, Edwin C.
    Housecroft, Catherine E.
    Schneider, Gabriel E.
    Zampese, Jennifer A.
    Bolink, Henk J.
    Pertegás, Antonio
    Roldan-Carmona, Cristina
    Dalton Transactions, 2014, 43 (12): : 4653 - 4667
  • [29] Red emitting [Ir(C N)2(N N)]+ complexes employing bidentate 2,2′:6′,2"- terpyridine ligands for light-emitting electrochemical cells
    Constable, Edwin C.
    Housecroft, Catherine E.
    Schneider, Gabriel E.
    Zampese, Jennifer A.
    Bolink, Henk J.
    Pertegas, Antonio
    Roldan-Carmona, Cristina
    DALTON TRANSACTIONS, 2014, 43 (12) : 4653 - 4667
  • [30] Re(I)(tricarbonyl)+ complexes with the 2-(2-pyridyl)-N-methyl-benzimidazole, 2-(2-pyridyl)benzoxazole and 2-(2-pyridyl)benzothiazole ligands -: syntheses, structures, electrochemical and spectroscopic studies
    Czerwieniec, R
    Kapturkiewicz, A
    Lipkowski, J
    Nowacki, J
    INORGANICA CHIMICA ACTA, 2005, 358 (09) : 2701 - 2710
12345