Efficient and complete dehydrogenation of hydrazine borane over a CoPt catalyst

被引:6
|
作者
Wu, Haochong [1 ]
Yao, Qilu [1 ]
Hu, Chenxi [1 ]
Long, Jianjun [1 ]
Zhou, Yuanlan [2 ]
Lu, Zhang-Hui [1 ]
机构
[1] Jiangxi Normal Univ, Inst Adv Mat IAM, Key Lab Energy Catalysis & Convers Nanchang, Coll Chem & Chem Engn, Nanchang 330022, Peoples R China
[2] Jiangxi Normal Univ, Sch Math & Stat, Nanchang 330022, Peoples R China
关键词
COMPLETE HYDROGEN GENERATION; NANOPARTICLES; METHANOLYSIS; HYDROLYSIS;
D O I
10.1039/d3cc03568a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Bimetallic CoPt alloy nanoparticles (NPs) immobilized on CeO2 nanorods (CoPt/CeO2) were synthesized by a facile wet-chemistry reduction method, which showed the highest catalytic efficiency reported to date for the complete dehydrogenation of hydrazine borane with a high TOF value of up to 5454 h-1 at 323 K. CeO2-supported CoPt NPs were synthesized via a simple and green wet-chemistry reduction method and used as robust catalysts for complete hydrogen production from hydrazine borane.
引用
收藏
页码:12116 / 12119
页数:4
相关论文
共 50 条
  • [21] Efficient Organocatalytic Dehydrogenation of Ammonia Borane
    Hasenbeck, Max
    Becker, Jonathan
    Gellrich, Urs
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (04) : 1590 - 1594
  • [22] Ultrasound-assisted synthesis of highly dispersed nickel nanoclusters on MXene for efficient dehydrogenation of hydrazine borane
    Liu, Weihong
    Guo, Feng
    Long, Jianjun
    Feng, Gang
    Huang, Minsong
    Lu, Zhang-Hui
    SURFACES AND INTERFACES, 2025, 56
  • [23] Ultrafine Ni-Pt Alloy Nanoparticles Grown on Graphene as Highly Efficient Catalyst for Complete Hydrogen Generation from Hydrazine Borane
    Zhang, Zhujun
    Lu, Zhang-Hui
    Chen, Xiangshu
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2015, 3 (06): : 1255 - 1261
  • [24] Innovation in the synthesis of hydrazine borane by mechanochemical method and hydrolysis of hydrazine borane with Pd/TiO2 catalyst
    Bayram, Ozge
    Murathan, Hatice Begum
    Angi, Okay Serkan
    Ozkan, Gulay
    Ozkan, Goksel
    MATERIALS CHEMISTRY AND PHYSICS, 2024, 319
  • [25] Noble-Metal-Free Ni-MoOx Nanoparticles Supported on BN as a Highly Efficient Catalyst toward Complete Decomposition of Hydrazine Borane
    Li, Si-Jia
    Kang, Xia
    Wulan, Ba-Ri
    Qu, Xian-Lin
    Zheng, Kun
    Han, Xiao-Dong
    Yan, Jun-Min
    SMALL METHODS, 2018, 2 (12):
  • [26] Hydrogen liberation from the hydrolytic dehydrogenation of hydrazine borane in acidic media
    Sen, Betul
    Savk, Aysun
    Kuyuldar, Esra
    Gulbay, Senem Karahan
    Sen, Fatih
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (38) : 17978 - 17983
  • [27] Palladium nanoparticles supported on chemically derived graphene: An efficient and reusable catalyst for the dehydrogenation of ammonia borane
    Metin, Onder
    Kayhan, Emine
    Ozkar, Saim
    Schneider, Jorg J.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (10) : 8161 - 8169
  • [28] Designing Metal-Free Frustrated Lewis Pairs Catalyst for the Efficient Dehydrogenation of Ammonia Borane
    Ma, Gongli
    Song, Guoliang
    Li, Zhen Hua
    CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (50) : 13238 - 13245
  • [29] La(OH)3-decorated NiFe nanoparticles as efficient catalyst for hydrogen evolution from hydrous hydrazine and hydrazine borane
    Zou, Hongtao
    Guo, Feng
    Luo, Minghong
    Yao, Qilu
    Lu, Zhang-Hui
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2020, 45 (20) : 11641 - 11650
  • [30] Controlled Synthesis of MOF-Encapsulated NiPt Nanoparticles toward Efficient and Complete Hydrogen Evolution from Hydrazine Borane and Hydrazine
    Zhang, Zhujun
    Zhang, Shiliang
    Yao, Qilu
    Chen, Xiangshu
    Lu, Zhang-Hui
    INORGANIC CHEMISTRY, 2017, 56 (19) : 11938 - 11945