Hydrogen liberation from the hydrolytic dehydrogenation of hydrazine borane in acidic media

被引：16
|
作者：
Sen, Betul [1 ]
Savk, Aysun [1 ]
Kuyuldar, Esra [1 ]
Gulbay, Senem Karahan [2 ]
Sen, Fatih [1 ]
机构：
[1] Dumlupinar Univ, Fac Arts & Sci, Dept Biochem, Sen Res Grp, Evliya Celebi Campus, TR-43100 Kutahya, Turkey
[2] Dokuz Eylul Univ, Fac Sci, Dept Chem, Tinaztepe Campus, TR-35160 Izmir, Turkey
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2018年 / 43卷 / 38期
关键词：
Acidic media; Hydrogen generation; Hydrolysis; Hydrazine borane; HIGHLY-ACTIVE CATALYSTS; AQUEOUS AMMONIA-BORANE; DIMETHYLAMINE-BORANE; ROOM-TEMPERATURE; GRAPHENE OXIDE; ALCOHOL OXIDATION; REUSABLE CATALYST; GENERATION SYSTEM; STORAGE MATERIALS; CARBON NANOTUBE;
D O I：
10.1016/j.ijhydene.2018.03.225
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Addressed herein, the hydrolytic dehydrogenation of hydrazine borane (NH4BH3, HB) was reported in acidic media using nitric acid (HNO3) as a catalyst at room conditions. The aqueous hydrazine borane was treated with HNO3 solution in different concentrations to liberate H-2. Besides, kinetic data were collected to idetificate the activation parameters, the effect of temperature, acid and hydrazine borane concentrations on the hydrogen production for the hydrolytic dehydrogenation of hydrazine borane in acidic media. It can be said that the acid catalyzed hydrazine borane system can be regarded as a simple system for hydrogen production. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：17978 / 17983
页数：6
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