Synthesis, Crystal Structure and Luminescence of One-dimensional Homochiral Terbium (Ⅲ) Coordination Polymers

被引：4

作者：

徐艳 ^{[1
,2
]}

李新星 ^{[1
,2
]}

王红侠 ^{[1
,2
]}

刘浩然 ^{[1
]}

陈梦琪 ^{[1
]}

窦强 ^{[1
]}

机构：

[1] Department of Materials Science and Engineering, Suqian College

[2] Industrial Research Institute, Suqian College

来源：

Chinese Journal of Structural Chemistry | 2020年 / 39卷 / 06期

关键词：

terbium(Ⅲ); crystal structure; luminescence; homochiral;

D O I：

10.14102/j.cnki.0254-5861.2011-2550

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

Enantiomerically pure lanthanide（Ⅲ）-based phosphonates are successfully synthesized by using（R）-or（S）-（1-phenylethylamino）-methylphosphonate acid（pempH;）, namely, R-or S-[Tb;（pempH;）;（pempH）;]-Cl;·H;O（R-Tb or S-Tb）, crystallizing in chiral space group P2;2;2;. Compound R-Tb shows a one-dimensional homochiral triple-stranded helical chain structure where the Tb（III） atoms are bridged by O-P-O units and μ;-O（P） bridge. The thermal analysis, photoluminescence as well as optically active properties of compounds R-Tb and S-Tb have also been investigated.

引用

页码：1044 / 1050

页数：7

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