Synthesis, Crystal Structure and Luminescence of One-dimensional Homochiral Terbium (Ⅲ) Coordination Polymers

被引：4
|
作者：
徐艳 [1 ,2 ]
李新星 [1 ,2 ]
王红侠 [1 ,2 ]
刘浩然 [1 ]
陈梦琪 [1 ]
窦强 [1 ]
机构：
[1] Department of Materials Science and Engineering, Suqian College
[2] Industrial Research Institute, Suqian College
来源：
Chinese Journal of Structural Chemistry | 2020年 / 39卷 / 06期
关键词：
terbium(Ⅲ); crystal structure; luminescence; homochiral;
D O I：
10.14102/j.cnki.0254-5861.2011-2550
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
Enantiomerically pure lanthanide（Ⅲ）-based phosphonates are successfully synthesized by using（R）-or（S）-（1-phenylethylamino）-methylphosphonate acid（pempH;）, namely, R-or S-[Tb;（pempH;）;（pempH）;]-Cl;·H;O（R-Tb or S-Tb）, crystallizing in chiral space group P2;2;2;. Compound R-Tb shows a one-dimensional homochiral triple-stranded helical chain structure where the Tb（III） atoms are bridged by O-P-O units and μ;-O（P） bridge. The thermal analysis, photoluminescence as well as optically active properties of compounds R-Tb and S-Tb have also been investigated.
引用
收藏
页码：1044 / 1050
页数：7
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