NITROXIDE-MEDIATED FREE RADICAL SYNTHESIS OF MESOGEN-JACKETED LIQUID CRYSTAL POLYMERS

被引：0
|
作者：
Xin-hua Wan
Hui-lin Tu
Ying-feng Tu
Dong Zhang
Ling Sun
Qi-feng Zhou
Yu-ping Dong
Mao Tang Department of Polymer Science & Engineering
机构：
来源：
Chinese Journal of Polymer Science | 1999年 / 02期
基金：
中国国家自然科学基金;
关键词：
TEMPO; Living" free radical polymerization; Mesogen-jacketed liquid crystal polymer; Mesophase polymerization;
D O I：
暂无
中图分类号：
TQ316.322 [];
学科分类号：
摘要：
The first TEMPO-mediated "living" free radical polymerization of liquid crystallinemonomer, 2, 5-bis[(4-methoxyphenyl)oxycarbonyl]styrene(MPCS), was carried out at 130℃ withBPO as an initiator. The molecular weight of the polymer can be varied from rather low values to highvalues while maintaining narrow polydispersity. It was observed that the polymerization of MPCSproceeded much faster than that of styrene. A tentative explanation for this fast polymerization wassuggested.
引用
收藏
页码：189 / 192
页数：4
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