NITROXIDE-MEDIATED FREE RADICAL SYNTHESIS OF MESOGEN-JACKETED LIQUID CRYSTAL POLYMERS

被引：0
|
作者：
Xin-hua Wan
Hui-lin Tu
Ying-feng Tu
Dong Zhang
Ling Sun
Qi-feng Zhou
Yu-ping Dong
Mao Tang Department of Polymer Science & Engineering
机构：
来源：
Chinese Journal of Polymer Science | 1999年 / 02期
基金：
中国国家自然科学基金;
关键词：
TEMPO; Living" free radical polymerization; Mesogen-jacketed liquid crystal polymer; Mesophase polymerization;
D O I：
暂无
中图分类号：
TQ316.322 [];
学科分类号：
摘要：
The first TEMPO-mediated "living" free radical polymerization of liquid crystallinemonomer, 2, 5-bis[(4-methoxyphenyl)oxycarbonyl]styrene(MPCS), was carried out at 130℃ withBPO as an initiator. The molecular weight of the polymer can be varied from rather low values to highvalues while maintaining narrow polydispersity. It was observed that the polymerization of MPCSproceeded much faster than that of styrene. A tentative explanation for this fast polymerization wassuggested.
引用
收藏
页码：189 / 192
页数：4
相关论文
共 50 条
  • [31] Novel semirigid water-soluble thermoresponsive polymers based on mesogen-jacketed liquid crystal polymers
    Wang, Chunhua
    Du, Fangkai
    Xie, Helou
    Zhang, Hailiang
    Chen, Erqiang
    Zhou, Qifeng
    CHEMICAL COMMUNICATIONS, 2010, 46 (18) : 3155 - 3157
  • [32] Synthesis and characterization of a new series of "mesogen-jacketed liquid crystal polymers" based on the newly synthesized vinylterephthalic acid
    Zhang, D
    Liu, YX
    Wan, XH
    Zhou, QF
    MACROMOLECULES, 1999, 32 (16) : 5183 - 5185
  • [33] Influence of molecular weight on liquid crystalline behavior of linear and star mesogen-jacketed liquid crystal polymers
    Wang, XZ
    Zhang, HL
    Chen, EQ
    Wang, XY
    Zhou, QF
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (15) : 3232 - 3244
  • [34] Design, synthesis, and characterization of bent-core mesogen-jacketed liquid crystalline polymers
    Chen, XF
    Tenneti, KK
    Li, CY
    Bai, YW
    Zhou, R
    Wan, XH
    Fan, XH
    Zhou, QF
    MACROMOLECULES, 2006, 39 (02) : 517 - 527
  • [35] Synthesis and Characterization of Mesogen-Jacketed Liquid Crystalline Polymers through Hydrogen-Bonding
    Xu, Yiding
    Qu, Wei
    Yang, Qian
    Zheng, Jukuan
    Shen, Zhihao
    Fan, Xinghe
    Zhou, Qifeng
    MACROMOLECULES, 2012, 45 (06) : 2682 - 2689
  • [36] Helical columnar phase of mesogen-jacketed liquid crystal polymers for efficient circularly polarized luminescence
    Liu, Zui
    Deng, Fengyu
    Fan, Chunyan
    Yuan, Yongjie
    Zhang, Hailiang
    JOURNAL OF MATERIALS CHEMISTRY C, 2024, 12 (16) : 5896 - 5907
  • [37] Mesogen-jacketed liquid crystalline polymers and elastomers bearing polynorbornene backbone
    Yang, Hong
    Zhang, Fei
    Lin, Bao-Ping
    Keller, Patrick
    Zhang, Xue-Qin
    Sun, Ying
    Guo, Ling-Xiang
    JOURNAL OF MATERIALS CHEMISTRY C, 2013, 1 (07) : 1482 - 1490
  • [38] Synthesis and Characterization of a Mesogen-Jacketed Polyelectrolyte
    Qu, Wei
    Zhu, Xingqi
    Chen, Jiahui
    Niu, Lin
    Liang, Dehai
    Fan, Xinghe
    Shen, Zhihao
    Zhou, Qifeng
    MACROMOLECULES, 2014, 47 (08) : 2727 - 2735
  • [39] Poly(vinyl benzoate)-backbone mesogen-jacketed liquid crystalline polymers
    Yang, Hong
    Lv, You-Jing
    Xu, Ming
    Wang, Jun
    Lin, Bao-Ping
    Guo, Ling-Xiang
    Chen, Er-Qiang
    POLYMER CHEMISTRY, 2015, 6 (37) : 6709 - 6719
  • [40] Synthesis and properties of comb polymers with semirigid mesogen-jacketed polymers as side chains
    Ma, Ziyue
    Zheng, Cui
    Shen, Zhihao
    Liang, Dehai
    Fan, Xinghe
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (05) : 918 - 926
12345