NITROXIDE-MEDIATED FREE RADICAL SYNTHESIS OF MESOGEN-JACKETED LIQUID CRYSTAL POLYMERS

被引：0
|
作者：
Xin-hua Wan
Hui-lin Tu
Ying-feng Tu
Dong Zhang
Ling Sun
Qi-feng Zhou
Yu-ping Dong
Mao Tang Department of Polymer Science & Engineering
机构：
来源：
Chinese Journal of Polymer Science | 1999年 / 02期
基金：
中国国家自然科学基金;
关键词：
TEMPO; Living" free radical polymerization; Mesogen-jacketed liquid crystal polymer; Mesophase polymerization;
D O I：
暂无
中图分类号：
TQ316.322 [];
学科分类号：
摘要：
The first TEMPO-mediated "living" free radical polymerization of liquid crystallinemonomer, 2, 5-bis[(4-methoxyphenyl)oxycarbonyl]styrene(MPCS), was carried out at 130℃ withBPO as an initiator. The molecular weight of the polymer can be varied from rather low values to highvalues while maintaining narrow polydispersity. It was observed that the polymerization of MPCSproceeded much faster than that of styrene. A tentative explanation for this fast polymerization wassuggested.
引用
收藏
页码：189 / 192
页数：4
相关论文
共 50 条
  • [1] Nitroxide-mediated free radical synthesis of mesogen-jacketed liquid crystal polymers
    Wan, XH
    Tu, HL
    Tu, YF
    Zhang, D
    Sun, L
    Zhou, QF
    Dong, YP
    Tang, M
    CHINESE JOURNAL OF POLYMER SCIENCE, 1999, 17 (02) : 189 - 192
  • [2] Nitroxide-mediated 'living' free radical synthesis of novel rod-coil diblock copolymers with polystyrene and mesogen-jacketed liquid-crystal polymer segments
    Wan, XH
    Tu, YF
    Zhang, D
    Zhou, QF
    POLYMER INTERNATIONAL, 2000, 49 (03) : 243 - 247
  • [3] Design and synthesis of a series of novel mesogen-jacketed liquid crystal polymers
    Tu, HL
    Yu, ZN
    Wan, XH
    Chen, XF
    Zhou, QF
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2000, 21 (06): : 985 - 987
  • [4] Design and Synthesis of a Series of Novel Mesogen-Jacketed Liquid Crystal Polymers
    Tu, Hui-Lin
    Yu, Zhen-Ning
    Wan, Xin-Hua
    Chen, Xiao-Fang
    Zhou, Qi-Feng
    Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 2000, 21 (06):
  • [5] Mesogen-jacketed liquid crystalline polymers
    Chen, Xiao-Fang
    Shen, Zhihao
    Wan, Xin-Hua
    Fan, Xing-He
    Chen, Er-Qiang
    Ma, Yuguo
    Zhou, Qi-Feng
    CHEMICAL SOCIETY REVIEWS, 2010, 39 (08) : 3072 - 3101
  • [6] Mesogen-jacketed liquid crystalline polymers via stable free radical polymerization
    Pragliola, S
    Ober, CK
    Mather, PT
    Jeon, HG
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1999, 200 (10) : 2338 - 2344
  • [7] Recent progress of functional mesogen-jacketed liquid crystal polymers
    Wu Bo-xi
    Luo Zhi-wang
    Deng Yuan
    Wang Ping
    Xie He-lou
    CHINESE JOURNAL OF LIQUID CRYSTALS AND DISPLAYS, 2022, 37 (02) : 169 - 185
  • [8] Synthesis and Properties of Mesogen-Jacketed Liquid Crystalline Polymers Containing Bistolane Mesogen
    Zhang, Zhen Lin
    Zhang, Lan Ying
    Shen, Zhi Hao
    Xing, Guang Zhong
    Fan, Xing He
    Zhou, Qi Feng
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (21) : 4627 - 4639
  • [9] Synthesis of Mesogen-Jacketed liquid crystalline polymers in chiral conditions
    Mi, QD
    Wan, XH
    Zhou, QF
    ACTA POLYMERICA SINICA, 2000, (02) : 253 - 256
  • [10] Synthesis and properties of new mesogen-jacketed liquid crystalline polymers
    Mi, Qi-Ding
    Zhou, Qi-Feng
    Chinese Journal of Polymer Science (English Edition), 2000, 18 (02): : 139 - 148
12345