Synthesis, Crystal Structure and Characterization of a New Hydrogen-bonded Organic Framework

被引：0

作者：

孙静 ^{[1
]}

刘海雄 ^{[2
]}

刘天赋 ^{[3
]}

机构：

[1] School of Physical Science and Technology, ShanghaiTech University

[2] Jinshan College, Fujian Agriculture and Forestry University

[3] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences

来源：

ChineseJournalofStructuralChemistry | 2021年 / 40卷 / 08期

关键词：

tetrahydroyquinone; diethylamine; hydrogen-bonded organic framework;

D O I：

10.14102/j.cnki.0254-5861.2011-3113

中图分类号：

TB34 [功能材料]; O641.3 [分子间的相互作用、超分子化学];

学科分类号：

080501 ;

摘要：

The hydrogen-bonded organic framework(PFC-32), constructed by tetrahydroxyquinone(THQN)and diethylamine(DEA), was readily prepared via hydrothermal synthesis in DEF(N,N-diethylformamide).PFC-32 was characterized by PXRD, IR, UV-Vis, TGA and photoluminescence(PL). Single crystal analysis reveals that PFC-32 shows a three-dimensional(3 D) framework, where the THQN anions are coplanar and separated by DEA cations. PFC-32 displays intrinsic photoluminescence property owing to the alleviation of the aggregation-caused quenching(ACQ) effect caused by π-π stacking.

引用

页码：1082 / 1087

页数：6

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