Synthesis, Crystal Structure and Characterization of a New Hydrogen-bonded Organic Framework

被引：0
|
作者：
孙静 [1 ]
刘海雄 [2 ]
刘天赋 [3 ]
机构：
[1] School of Physical Science and Technology, ShanghaiTech University
[2] Jinshan College, Fujian Agriculture and Forestry University
[3] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
来源：
ChineseJournalofStructuralChemistry | 2021年 / 40卷 / 08期
关键词：
tetrahydroyquinone; diethylamine; hydrogen-bonded organic framework;
D O I：
10.14102/j.cnki.0254-5861.2011-3113
中图分类号：
TB34 [功能材料]; O641.3 [分子间的相互作用、超分子化学];
学科分类号：
080501 ;
摘要：
The hydrogen-bonded organic framework(PFC-32), constructed by tetrahydroxyquinone(THQN)and diethylamine(DEA), was readily prepared via hydrothermal synthesis in DEF(N,N-diethylformamide).PFC-32 was characterized by PXRD, IR, UV-Vis, TGA and photoluminescence(PL). Single crystal analysis reveals that PFC-32 shows a three-dimensional(3 D) framework, where the THQN anions are coplanar and separated by DEA cations. PFC-32 displays intrinsic photoluminescence property owing to the alleviation of the aggregation-caused quenching(ACQ) effect caused by π-π stacking.
引用
收藏
页码：1082 / 1087
页数：6
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