Magneto-Structural Correlation in μ-Hydroxo-μ-Carboxylato Hetero-Bridged Dinuclear Oxidovanadium(IV) Complexes

被引：0
|
作者：
Yoshida, Ryo [1 ]
Koikawa, Masayuki [1 ]
Tokii, Tadashi [1 ]
机构：
[1] Saga Univ, Fac Sci & Engn, Dept Chem & Appl Chem, Honjo 1, Saga 8408502, Japan
来源：
CRYSTALS | 2024年 / 14卷 / 12期
关键词：
dinuclear complex; oxidovanadium; crystal structure; hetero bridge; tripodal ligand; magnetic property; CRYSTAL-STRUCTURE; MAGNETIC-PROPERTIES; VANADIUM(IV); MAGNETOCHEMISTRY;
D O I：
10.3390/cryst14121072
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Hetero-bridged dinuclear oxidovanadium(IV) complexes, [(VO)(2){HB(pz}(3)}(2)(mu-OH)(mu-O2CR)] [R = C2H5, 1; (CH3)(3)C, 2; (CH3)(3)CCH2, 3; Ph2CH, 4; Ph3C, 5; PhCH2CH2, and 6; {HB(pz)(3)}(-) = hydrotris(pyrazolyl)borate], were synthesized and characterized using X-ray crystallography, infrared spectroscopy, UV-VIS spectroscopy, and elemental analysis. Structure analysis revealed that these complexes adopt a mu-hydroxo-mu-carboxylato hetero-bridged dinuclear structure. Magnetic measurements revealed ferromagnetic interactions (J similar to +20 cm(-1)) between two V(IV) ions.
引用
收藏
页数：15
相关论文
共 50 条
  • [21] Synthesis and magneto-structural correlation of a new maleato bridged copper(II) coordination polymer
    Shit, Shyamapada
    Chakraborty, Joy
    Das, Anamika
    Yap, Glenn P. A.
    El Fallah, M. S.
    Mitra, Samiran
    STRUCTURAL CHEMISTRY, 2007, 18 (03) : 317 - 323
  • [22] Synthesis and magneto-structural correlation of a new maleato bridged copper(II) coordination polymer
    Shyamapada Shit
    Joy Chakraborty
    Anamika Das
    Glenn P. A. Yap
    M. S. El. Fallah
    Samiran Mitra
    Structural Chemistry, 2007, 18 : 317 - 323
  • [23] Magneto-structural correlation, antioxidant, DNA interaction and growth inhibition activities of new chloro-bridged phenolate complexes
    Gurumoorthy, Perumal
    Mahendiran, Dharmasivam
    Prabhu, Durai
    Arulvasu, Chinnasamy
    Rahiman, Aziz Kalilur
    RSC ADVANCES, 2014, 4 (81) : 42855 - 42872
  • [24] Structural characterization and magnetic properties of triply carboxylato-bridged dinuclear copper(II) complexes
    Matsushima, H
    Koikawa, M
    Nukada, R
    Mikuriya, M
    Tokii, T
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1999, 72 (05) : 1025 - 1035
  • [25] Dinuclear Copper(II) Complex with Intramolecular O-H⋅⋅⋅O Hydrogen Bonding: Magneto-Structural Correlation for Acylhydrazone-Based Phenoxido Bridged Copper(II) Complexes
    Boehme, Michael
    Mohanty, Monalisa
    Lima, Sudhir
    Buchholz, Axel
    Goerls, Helmar
    Dinda, Rupam
    Plass, Winfried
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2024, 27 (36)
  • [26] Study on the Magneto-Structural Correlation of a New Dinuclear Cobalt(II) Complex with Double μ-Phenoxo Bridges
    Song, Xiao-jiao
    Xue, Xiao-ming
    ACS OMEGA, 2020, 5 (14): : 8347 - 8354
  • [27] Magneto-structural correlations in dinuclear d(1)-d(1) complexes: Structure and magnetochemistry of two ferromagnetically coupled vanadium(IV) dimers
    Plass, W
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (06): : 627 - 631
  • [28] Water induced spin-crossover behaviour and magneto-structural correlation in octacyanotungstate(IV)-based iron(II) complexes
    Wei, Rong-Min
    Kong, Ming
    Cao, Fan
    Li, Jing
    Pu, Tian-Cheng
    Yang, Li
    Zhang, Xiu-Ling
    Song, You
    DALTON TRANSACTIONS, 2016, 45 (46) : 18643 - 18652
  • [29] Doubly chloro bridged dimeric copper(II) complex: magneto-structural correlation and anticancer activity
    Sikdar, Yeasin
    Modak, Ritwik
    Bose, Dipayan
    Banerjee, Saswati
    Bienko, Dariusz
    Zierkiewicz, Wiktor
    Bienko, Alina
    Das Saha, Krishna
    Goswami, Sanchita
    DALTON TRANSACTIONS, 2015, 44 (19) : 8876 - 8888
  • [30] Theoretical studies on dicopper(II) complexes of phenoxido-bridged ligands: Magneto-structural correlations
    Luo, Shuchang
    Su, Yangyang
    Wang, Yingli
    Sun, Xiaoyuan
    COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2022, 1207
12345