A σ,π-type monocarborane copper acetylide for regioselective 1,4-disubstituted 1,2,3-triazoles

被引：0
|
作者：
Zhang, Kang [1 ]
Feng, Luting [1 ]
Jin, Yujie [2 ]
Liu, Jiyong [2 ]
Duttwyler, Simon [2 ]
机构：
[1] Shaoxing Univ, Yuanpei Coll, Qunxian Rd 2799, Shaoxing 312000, Peoples R China
[2] Zhejiang Univ, Dept Chem, Yuhangtang Rd 866, Hangzhou 310058, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 20期
关键词：
PHARMACOPHORES; CARBORANES; ANIONS;
D O I：
10.1039/d5cc00077g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A sigma,pi-bis(copper) acetylide complex, (CB11H11-12-C 00000000000000000 00000000000000000 00000000000000000 01111111111111110 00000000000000000 01111111111111110 00000000000000000 01111111111111110 00000000000000000 00000000000000000 00000000000000000 C)Cu2(PiPr3)3 (2), enables the formation of regioselective 1,4-disubstituted 1,2,3-triazoles containing monocarborane anion [CB11H12]-via CuAAC with organic azides under mild conditions. This method achieves 1,2,3-triazolylated monocarboranes (3) in up to 97% yield, including a luminescent compound with optoelectronic potential.
引用
收藏
页码：4026 / 4029
页数：4
相关论文
共 50 条
  • [31] General Method for the Synthesis of 1,4-Disubstituted 5-Halo-1,2,3-triazoles
    Gribanov, Pavel S.
    Topchiy, Maxim A.
    Karsakova, Iuliia V.
    Chesnokov, Gleb A.
    Smirnov, Alexander Yu.
    Minaeva, Lidiya I.
    Asachenko, Andrey F.
    Nechaev, Mikhail S.
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 2017 (35) : 5225 - 5230
  • [32] One-pot, efficient, and regioselective syntheses of 1,4-disubstituted 1,2,3-triazoles using aryldiazonium silica sulfates in water
    Zarei, Amin
    TETRAHEDRON LETTERS, 2012, 53 (38) : 5176 - 5179
  • [33] Ionic Liquid Catalyzed Efficient Regioselective Synthesis of 1,4-Disubstituted 1,2,3-Triazoles Under Metal and Solvent Free Conditions
    Banday, Abid H.
    Hruby, Victor J.
    CURRENT ORGANOCATALYSIS, 2021, 8 (02) : 223 - 227
  • [34] Recent Advancements in 1,4-Disubstituted 1H-1,2,3-Triazoles as Potential Anticancer Agents
    Lal, Kashmiri
    Yadav, Pinki
    ANTI-CANCER AGENTS IN MEDICINAL CHEMISTRY, 2018, 18 (01) : 21 - 37
  • [35] Conventional and microwave assisted synthesis of 1,4-disubstituted 1,2,3-triazoles from Huisgen cycloaddition
    Sarmiento-Sanchez, Juan I.
    Ochoa-Teran, Adrian
    Rivero, Ignacio A.
    ARKIVOC, 2011, : 177 - 188
  • [36] Recent Catalysts Used in the Synthesis of 1,4-Disubstituted 1,2,3-Triazoles by Heterogeneous and Homogeneous Methods
    Noriega, Saul
    Leyva, Elisa
    Moctezuma, Edgar
    Flores, Luisa
    Loredo-Carrillo, Silvia
    CURRENT ORGANIC CHEMISTRY, 2020, 24 (05) : 536 - 549
  • [37] Efficient synthesis, antitubercular and antimicrobial evaluation of 1,4-disubstituted 1,2,3-triazoles with amide functionality
    C. P. Kaushik
    Ashima Pahwa
    Dharmendra Singh
    Krishan Kumar
    Raj Luxmi
    Monatshefte für Chemie - Chemical Monthly, 2019, 150 : 1127 - 1136
  • [38] Synthesis and antimicrobial evaluation of some novel thiomorpholine derived 1,4-disubstituted 1,2,3-triazoles
    Battula, Kumaraswamy
    Narsimha, Sirassu
    Nagavelli, Vasudevareddy
    Bollepelli, Priyanka
    Rao, Mutheneni Srinivasa
    JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2016, 81 (03) : 233 - 242
  • [39] Recent progress in the Cu-catalyzed multicomponent synthesis of 1,4-disubstituted 1,2,3-triazoles
    Anand, Akash
    Kumar, Rajneesh
    Maity, Jyotirmoy
    Maikhuri, Vipin K. K.
    SYNTHETIC COMMUNICATIONS, 2023, 53 (05) : 345 - 375
  • [40] Design, synthesis, anticancer and antioxidant activities of amide linked 1,4-disubstituted 1,2,3-triazoles
    Kaushik, C. P.
    Sangwan, Jyoti
    Luxmi, Raj
    Kumar, Devinder
    Kumar, Deepak
    Das, Ashutosh
    Kumar, Ashwani
    Singh, Dharmendra
    JOURNAL OF MOLECULAR STRUCTURE, 2021, 1226
12345