A σ,π-type monocarborane copper acetylide for regioselective 1,4-disubstituted 1,2,3-triazoles

被引：0
|
作者：
Zhang, Kang [1 ]
Feng, Luting [1 ]
Jin, Yujie [2 ]
Liu, Jiyong [2 ]
Duttwyler, Simon [2 ]
机构：
[1] Shaoxing Univ, Yuanpei Coll, Qunxian Rd 2799, Shaoxing 312000, Peoples R China
[2] Zhejiang Univ, Dept Chem, Yuhangtang Rd 866, Hangzhou 310058, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 20期
关键词：
PHARMACOPHORES; CARBORANES; ANIONS;
D O I：
10.1039/d5cc00077g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A sigma,pi-bis(copper) acetylide complex, (CB11H11-12-C 00000000000000000 00000000000000000 00000000000000000 01111111111111110 00000000000000000 01111111111111110 00000000000000000 01111111111111110 00000000000000000 00000000000000000 00000000000000000 C)Cu2(PiPr3)3 (2), enables the formation of regioselective 1,4-disubstituted 1,2,3-triazoles containing monocarborane anion [CB11H12]-via CuAAC with organic azides under mild conditions. This method achieves 1,2,3-triazolylated monocarboranes (3) in up to 97% yield, including a luminescent compound with optoelectronic potential.
引用
收藏
页码：4026 / 4029
页数：4
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