Structural modified polythiophene by cross-linking alkyl chains

被引：0
|
作者：
Mangold, Klaus-Michael [1 ]
Jüttner, Klaus [1 ]
机构：
[1] Karl-Winnacker-Institut, DECHEMA e. V., PF 150 104, D-60061 Frankfurt am Main, Germany
来源：
Synthetic Metals | 1999年 / 101卷 / 01期
关键词：
Crosslinking - Cyclic voltammetry - Electrochemistry - Electropolymerization - Mathematical models - Redox reactions;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
This report describes the electrochemical redox behavior of the alkyl bridge cross-linked polythiophene derivative poly(1,12-bis(3-thienyl-)dodecane) (PTC12T) compared to the non bridged poly(3-dodecyl-)thiophene (PC12T) and poly(3-hexyl-)thiophene (PC6T). Copolymers of α, ω-bis(3-thienyl-)alkanes with thiophene are also characterized. Through cyclic voltammetric measurements, it is shown that the transformation of reduced polymers into oxidized state is temperature dependent and oxidized polymers relax to the reduced state.
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页码：71 / 72
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