FILM MEMBRANE ELECTRODES SELECTIVE FOR THE THIOCYANATE ION, BASED ON VARIOUS ION EXCHANGERS.

被引:0
|
作者
Grekovich, A.L. [1 ]
Materova, E.A. [1 ]
Didina, S.E. [1 ]
Silin, S.N. [1 ]
机构
[1] Leningrad, Leningrad, Russia
关键词
D O I
暂无
中图分类号
学科分类号
摘要
The authors investigated the selective properties of polymer film membrane electrodes with thiocyanate function based on ten ion exchangers which differ in the nature of the radicals in the quaternary ammonium base and also in the nature of the ″onium″ base itself. They find that all the ion-exchange materials investigated (except for cetyltrimethylammonium thiocyanate), namely various representatives of symmetric and asymmetric ammonium bases, a phosphonium base, and a metallic derivative of phenanthroline, are suitable for obtaining highly specific membrane electrodes for the thiocyanate ion. These film electrodes are recommended for extensive use in determining the activity (or concentration) of thiocyanate ions in solutions with complex compositions.
引用
收藏
页码:686 / 690
相关论文
共 50 条
  • [41] GAS SENSORS BASED ON ION-SELECTIVE POLYMER MEMBRANE ELECTRODES
    MEYERHOFF, ME
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 20 - ANYL
  • [42] THE INFLUENCE OF EXTRACTION PROCESSES ON THE FUNCTION OF LIQUID AND FILM MEMBRANE ION-SELECTIVE ELECTRODES
    RAKHMANKO, EM
    YEGOROV, VV
    GULEVICH, AL
    LUSHCHIK, YF
    SELECTIVE ELECTRODE REVIEWS, 1991, 13 (01): : 5 - 111
  • [43] SYNTHESIS AND PHYSICOCHEMICAL STUDIES OF SOME NEW AMPHOTERIC ION EXCHANGERS.
    KAPADIA, R.N.
    DALAL, A.K.
    1600, (V 27):
  • [44] Reactive-extraction equilibria of cations and anions with ion exchangers.
    Mörters, MF
    Roos, M
    Bart, HJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U763 - U763
  • [45] Novel class of solid-solution, inorganic ion exchangers.
    Nyman, M
    Nenoff, TM
    Balmer, ML
    Su, YL
    Navrotsky, A
    Xu, HW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U878 - U878
  • [47] FILM ION-SELECTIVE ELECTRODES WITH SOLID CONTACT
    GREKOVICH, AL
    VESTNIK LENINGRADSKOGO UNIVERSITETA SERIYA FIZIKA KHIMIYA, 1980, (03): : 68 - 73
  • [48] Preparation and application of iodide-mercury selective membrane electrode based on ion exchangers
    Somer, O
    Kalayci, S
    Ekmekci, G
    SENSORS AND ACTUATORS B-CHEMICAL, 2001, 81 (01) : 122 - 127
  • [49] Acid-base properties of ion exchangers. II. Determination of the acidity parameters of ion exchangers with arbitrary functionality
    Soldatov, VS
    Sosinovich, ZI
    Mironova, TV
    REACTIVE & FUNCTIONAL POLYMERS, 2004, 58 (01): : 13 - 26
  • [50] FILM MEMBRANE ELECTRODES, SPECIFIC FOR THE POTASSIUM-ION
    NOROV, SK
    TASHMUKHAMEDOVA, AK
    SAIFULLINA, NZ
    JOURNAL OF ANALYTICAL CHEMISTRY OF THE USSR, 1982, 37 (02): : 169 - 171