Improving the properties of the proton exchange membranes by introducing α-methylstyrene in the pre-irradiation induced graft polymerization

被引：0
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作者：
Li, Jingye [1 ]
Muto, Fumihiro [1 ]
Miura, Takaharu [1 ,2 ]
Oshima, Akihiro [1 ,2 ]
Washio, Masakazu [1 ]
Ikeda, Shigetoshi [2 ]
Iida, Minoru [2 ]
Tabata, Yoneho [2 ,3 ]
Matsuura, Chihiro [3 ]
Katsumura, Yousuke [3 ]
机构：
[1] Advanced Research Institute for Science and Engineering, Waseda University, 3-4-1, Okubo, Shinjuku, Tokyo, 169-8555, Japan
[2] RAYTECH Corporation, Sousyu Bldg 402 4-40-13 Takadanobaba, Shinjuku, Tokyo, 169-0075, Japan
[3] The University of Tokyo, 7-3-1, Hongo, Bunkyo, Tokyo, 113-8656, Japan
来源：
European Polymer Journal | 2006年 / 42卷 / 06期
关键词：
New proton exchange membranes (PEMs) were prepared by pre-irradiation induced grafting of α-methylstyrene (AMS)/styrene (STY)/divinylbenzene (DVB) into the crosslinked polytetrafluoroethylene (RX-PTFE) films and successively sulfonated. The new PEMs showed the improved glass transition temperature and chemical stability as compared with the PEMs prepared by pre-irradiation induced grafting of STY/DVB. The balance of the cost; grafting kinetic; thermal properties and the properties of the resulted proton exchange membrane is the key point of this work. © 2005 Elsevier Ltd. All rights reserved;
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页码：1222 / 1228
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