Improving the properties of the proton exchange membranes by introducing α-methylstyrene in the pre-irradiation induced graft polymerization

被引：0

作者：

Li, Jingye ^{[1
]}

Muto, Fumihiro ^{[1
]}

Miura, Takaharu ^{[1
,2
]}

Oshima, Akihiro ^{[1
,2
]}

Washio, Masakazu ^{[1
]}

Ikeda, Shigetoshi ^{[2
]}

Iida, Minoru ^{[2
]}

Tabata, Yoneho ^{[2
,3
]}

Matsuura, Chihiro ^{[3
]}

Katsumura, Yousuke ^{[3
]}

机构：

[1] Advanced Research Institute for Science and Engineering, Waseda University, 3-4-1, Okubo, Shinjuku, Tokyo, 169-8555, Japan

[2] RAYTECH Corporation, Sousyu Bldg 402 4-40-13 Takadanobaba, Shinjuku, Tokyo, 169-0075, Japan

[3] The University of Tokyo, 7-3-1, Hongo, Bunkyo, Tokyo, 113-8656, Japan

来源：

European Polymer Journal | 2006年 / 42卷 / 06期

关键词：

New proton exchange membranes (PEMs) were prepared by pre-irradiation induced grafting of α-methylstyrene (AMS)/styrene (STY)/divinylbenzene (DVB) into the crosslinked polytetrafluoroethylene (RX-PTFE) films and successively sulfonated. The new PEMs showed the improved glass transition temperature and chemical stability as compared with the PEMs prepared by pre-irradiation induced grafting of STY/DVB. The balance of the cost; grafting kinetic; thermal properties and the properties of the resulted proton exchange membrane is the key point of this work. © 2005 Elsevier Ltd. All rights reserved;

D O I：

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中图分类号：

学科分类号：

摘要：

Journal article (JA)

引用

页码：1222 / 1228

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