Metalloporphyrinic metal-organic frameworks for enhanced photocatalytic degradation of a mustard gas simulant

被引：1
|
作者：
Quon, Alisa S. [1 ]
Manriquez, Doroteo [1 ]
Nguyen, Anna [1 ,7 ]
Papazyan, Edgar K. [1 ]
Wijeratne, Pavithra [1 ]
An, Lun [2 ]
Qi, Long [2 ]
Tang, Matthew J. [1 ]
Ready, Austin D. [3 ]
Farha, Omar K. [4 ,5 ,6 ]
Liu, Yangyang [1 ]
机构：
[1] Calif State Univ Los Angeles, Dept Chem & Biochem, 5151 State Univ Dr, Los Angeles, CA 90032 USA
[2] Iowa State Univ, US DOE Ames Natl Lab, Ames, IA 50011 USA
[3] Univ Calif Los Angeles, Dept Chem & Biochem, 607 Charles E Young Dr East, Los Angeles, CA 90095 USA
[4] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[5] Northwestern Univ, Int Inst Nanotechnol IIN, Evanston, IL 60208 USA
[6] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA
[7] Calif Univ Sci & Med, Colton, CA 92324 USA
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 61卷 / 01期
关键词：
SELECTIVE PHOTOOXIDATION; PORPHYRIN; AGENT;
D O I：
10.1039/d4cc03890h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four metalloporphyrinic metal-organic frameworks (MOFs) were successfully synthesized and exhibited enhanced activities for the photooxidation of a sulfur mustard simulant, 2-chloroethyl ethyl sulfide (CEES). Among them, a Sn-porphyrin functionalized 2D MOF, namely CSLA-21-NH2(Sn), showed a half-life of 1.5 min for CEES oxidation under blue LED, featuring as one of the fastest photocatalysts for CEES degradation.
引用
收藏
页码：77 / 80
页数：5
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