Metalloporphyrinic metal-organic frameworks for enhanced photocatalytic degradation of a mustard gas simulant

被引：1

作者：

Quon, Alisa S. ^{[1
]}

Manriquez, Doroteo ^{[1
]}

Nguyen, Anna ^{[1
,7
]}

Papazyan, Edgar K. ^{[1
]}

Wijeratne, Pavithra ^{[1
]}

An, Lun ^{[2
]}

Qi, Long ^{[2
]}

Tang, Matthew J. ^{[1
]}

Ready, Austin D. ^{[3
]}

Farha, Omar K. ^{[4
,5
,6
]}

Liu, Yangyang ^{[1
]}

机构：

[1] Calif State Univ Los Angeles, Dept Chem & Biochem, 5151 State Univ Dr, Los Angeles, CA 90032 USA

[2] Iowa State Univ, US DOE Ames Natl Lab, Ames, IA 50011 USA

[3] Univ Calif Los Angeles, Dept Chem & Biochem, 607 Charles E Young Dr East, Los Angeles, CA 90095 USA

[4] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[5] Northwestern Univ, Int Inst Nanotechnol IIN, Evanston, IL 60208 USA

[6] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA

[7] Calif Univ Sci & Med, Colton, CA 92324 USA

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 61卷 / 01期

关键词：

SELECTIVE PHOTOOXIDATION; PORPHYRIN; AGENT;

D O I：

10.1039/d4cc03890h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four metalloporphyrinic metal-organic frameworks (MOFs) were successfully synthesized and exhibited enhanced activities for the photooxidation of a sulfur mustard simulant, 2-chloroethyl ethyl sulfide (CEES). Among them, a Sn-porphyrin functionalized 2D MOF, namely CSLA-21-NH2(Sn), showed a half-life of 1.5 min for CEES oxidation under blue LED, featuring as one of the fastest photocatalysts for CEES degradation.

引用

页码：77 / 80

页数：5

共 50 条

[1] Detoxification of a Mustard-Gas Simulant by Nanosized Porphyrin-Based Metal-Organic Frameworks
Pereira, Carla F.
Liu, Yangyang
Howarth, Ashlee
Figueira, Flavio
Rocha, Joao
Hupp, Joseph T.
Farha, Omar K.
Tome, Joao P. C.
Almeida Paz, Filipe A.
ACS APPLIED NANO MATERIALS, 2019, 2 (01) : 465 - 469
[2] Photocatalytic organic pollutants degradation in metal-organic frameworks
Wang, Chong-Chen
Li, Jian-Rong
Lv, Xiu-Liang
Zhang, Yan-Qiu
Guo, Guangsheng
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (09) : 2831 - 2867
[3] Functionalized metal-organic frameworks for photocatalytic degradation of organic pollutants in environment
Zhang, Xi
Wang, Jing
Dong, Xing-Xing
Lv, Yun-Kai
CHEMOSPHERE, 2020, 242
[4] Selective Photooxidation of a Mustard-Gas Simulant Catalyzed by a Porphyrinic Metal-Organic Framework
Liu, Yangyang
Howarth, Ashlee J.
Hupp, Joseph T.
Farha, Omar K.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (31) : 9001 - 9005
[5] Protective Fabrics: Metal-Organic Framework Textiles for Rapid Photocatalytic Sulfur Mustard Simulant Detoxification
Lee, Dennis T.
Jamir, Jovenal D.
Peterson, Gregory W.
Parsons, Gregory N.
MATTER, 2020, 2 (02) : 404 - 415
[6] Photocatalytic metal-organic frameworks for organic transformations
Yu, Xiao
Wang, Le
Cohen, Seth M.
CRYSTENGCOMM, 2017, 19 (29) : 4126 - 4136
[7] Improving the Efficiency of Mustard Gas Simulant Detoxification by Tuning the Singlet Oxygen Quantum Yield in Metal-Organic Frameworks and Their Corresponding Thin Films
Buru, Cassandra T.
Majewski, Marek B.
Howarth, Ashlee J.
Lavroff, Robert H.
Kung, Chung-Wei
Peters, Aaron W.
Goswami, Subhadip
Farha, Omar K.
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (28) : 23802 - 23806
[8] Role of N-Rich Coordination Environment in Metal-Organic Frameworks for Enhanced Photocatalytic Dye Degradation
Kumari, Priyanka
Panda, Tamas
CRYSTAL GROWTH & DESIGN, 2024, 24 (11) : 4493 - 4500
[9] Single-Chain Conjugated Polymer Guests Confined inside Metal-Organic Frameworks (MOFs): Boosting the Detection and Degradation of a Sulfur Mustard Simulant
Liu, Shuya
Guo, Yongxian
Jiang, Yifei
Gong, Yanjun
Hu, Qiongzheng
Yu, Li
ANALYTICAL CHEMISTRY, 2024, 96 (06) : 2333 - 2340
[10] Reusable photocatalytic metal-organic frameworks for organic transformations
Yu, Xiao
Cohen, Seth
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253

← 1 2 3 4 5 →