Effects of the main compositions in bath on the surface topography and electrocatalytic hydrogen evolution of Ni-Mo alloy films

被引:0
|
作者
Du J. [1 ]
Xie S. [1 ]
Li N. [2 ]
Xu L. [1 ]
机构
[1] School of Packaging and Materials Engineering, Hunan University of Technology, Zhuzhou
[2] School of Metallurgical Engineering, Hunan University of Technology, Zhuzhou
来源
Xu, Lijian | 1600年 / American Scientific Publishers卷 / 11期
基金
中国国家自然科学基金;
关键词
Cathode Polarization Curves; Electrocatalytic Activities; Hydrogen Evolution Reaction; Ni-Mo Alloy Electrodes;
D O I
10.1166/jamr.2016.1289
中图分类号
学科分类号
摘要
The Ni-Mo alloy electrodes were prepared by electrodeposition technique with citric acid as a complexing agent. The influence of main compositions in bath such as the concentration of Na2MoO4 • 2H2O, the concentration of NiSO4 •6H2O and the concentration of sodium citrate on the microstructure and surface morphology of Ni-Mo alloy electrodes were characterized by scanning electron microscope (SEM). The hydrogen evolution reaction of Ni-Mo alloy electrodes were investigated in alkaline solution by the method of the cathode polarization curves. The results showed that the excellent Ni-Mo alloy electrodes with excellent electrocatalytic activities for hydrogen evolution were obtained when the concentration of Na2MoO4 •2H2O was 15 g/L, the concentration of NiSO4 •6H2O was 40 g/L, the concentration of sodium citrate concentration was 40 g/L. Copyright © 2016 American Scientific Publishers All rights reserved.
引用
收藏
页码:50 / 54
页数:4
相关论文
共 50 条
  • [21] Surface morphology and electrochemical characterization of electrodeposited Ni-Mo nanocomposites as cathodes for hydrogen evolution
    Abdel-Karim, R.
    Halim, J.
    El-Raghy, S.
    Nabil, M.
    Waheed, A.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2012, 530 : 85 - 90
  • [22] Surface morphology and electrochemical characterization of electrodeposited Ni-Mo nanocomposites as cathodes for hydrogen evolution
    Elhachmi Guettaf Temam
    Hachemi Ben Temam
    Said Benramache
    Chinese Physics B, 2015, 24 (10) : 563 - 567
  • [23] Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution
    Krstajic, N. V.
    Jovic, V. D.
    Gajic-Krstajic, Lj
    Jovic, B. M.
    Antozzi, A. L.
    Martelli, G. N.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (14) : 3676 - 3687
  • [24] Ni-Mo alloy nanostructures as cathodic materials for hydrogen evolution reaction during seawater electrolysis
    Golgovici, Florentina
    Pumnea, Alexandru
    Petica, Aurora
    Manea, Adrian Cristian
    Brincoveanu, Oana
    Enachescu, Marius
    Anicai, Liana
    CHEMICAL PAPERS, 2018, 72 (08) : 1889 - 1903
  • [25] Preparation of Ni-Mo-Co Alloy Electrodes and Their Electrocatalytic Activities for Hydrogen Evolution
    Du, Jingjing
    Xie, Shaowen
    Li, Na
    Xu, Lijian
    NANOSCIENCE AND NANOTECHNOLOGY LETTERS, 2016, 8 (05) : 382 - 386
  • [26] Hydrogen evolution reaction activities of electrodeposited nanocrystalline Ni-Mo thin films in alkaline baths
    To, Dung T.
    Park, Sun Hwa
    Kim, Min Joong
    Cho, Hyun-Seok
    V. Myung, Nosang
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2023, 48 (23) : 8409 - 8417
  • [27] Preparation of Hierarchical Nanoporous Al-SiO2/Ni-Mo Composite Electrodes and Their Electrocatalytic Hydrogen Evolution
    Du, Jingjing
    Xie, Shaowen
    Li, Na
    Xu, Jianxiong
    Xu, Lijian
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2016, 16 (12) : 12635 - 12639
  • [28] Effect of anodic treatment on the electrocatalytic activity of electrodeposited Ni-Mo coatings as cathode materials for hydrogen evolution reaction
    Korniy, S. A.
    Halaichak, S. A.
    Chuchman, M. R.
    Vynar, V. A.
    Datsko, B. M.
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2025, 705
  • [29] Role of Oxidized Mo Species on the Active Surface of Ni-Mo Electrocatalysts for Hydrogen Evolution under Alkaline Conditions
    Bau, Jeremy A.
    Kozlov, Sergey M.
    Miguel Azofra, Luis
    Ould-Chikh, Samy
    Emwas, Abdul-Hamid
    Idriss, Hicham
    Cavallo, Luigi
    Takanabe, Kazuhiro
    ACS CATALYSIS, 2020, 10 (21) : 12858 - 12866
  • [30] Preparation and Hydrogen Evolution Properties of Nanoporous Ni, Ni-Mo Alloys and Their Oxides
    Zhou Qi
    Li Zhi-Yang
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2018, 34 (12) : 2188 - 2196