Copper-Catalyzed Synthesis of Sulfinic Esters via Oxidative Coupling of Thiols or Disulfides with Alcohols

被引：2

作者：

Taniguchi, Nobukazu ^{[1
]}

机构：

[1] Osaka Metropolitan Univ, Fac Liberal Arts Sci & Global Educ, Dept Dept Chem, Sakai, Osaka 5998531, Japan

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 13卷 / 08期

关键词：

TE BOND; NUCLEOPHILES; SE;

D O I：

10.1002/ajoc.202400131

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The copper-catalyzed coupling of thiols with alcohols was achieved under air atmosphere. The reaction proceeded smoothly in the presence of a base such as Cs2CO3 or Rb2CO3 affording sulfinic esters in good yields. Furthermore, disulfides were also available in the procedure. Both sulfide-groups on disulfide were efficiently consumed.

引用

页数：7

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