Copper-Catalyzed Synthesis of Sulfinic Esters via Oxidative Coupling of Thiols or Disulfides with Alcohols

被引：2
|
作者：
Taniguchi, Nobukazu [1 ]
机构：
[1] Osaka Metropolitan Univ, Fac Liberal Arts Sci & Global Educ, Dept Dept Chem, Sakai, Osaka 5998531, Japan
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 13卷 / 08期
关键词：
TE BOND; NUCLEOPHILES; SE;
D O I：
10.1002/ajoc.202400131
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The copper-catalyzed coupling of thiols with alcohols was achieved under air atmosphere. The reaction proceeded smoothly in the presence of a base such as Cs2CO3 or Rb2CO3 affording sulfinic esters in good yields. Furthermore, disulfides were also available in the procedure. Both sulfide-groups on disulfide were efficiently consumed.
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页数：7
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