Defunctionalization Enabled by Intramolecular Radical Aromatic Ipso Substitution

被引：0

作者：

Zhang, Qijing ^{[1
]}

Liu, Tinglan ^{[1
]}

Wu, Lili ^{[1
]}

Zhou, Cong-Ying ^{[1
]}

Wang, Chengming ^{[1
]}

机构：

[1] Jinan Univ, Coll Chem & Mat Sci, Guangzhou 511443, Guangdong, Peoples R China

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 36期

关键词：

NITROGEN-HETEROCYCLES; PHOTOREDOX CATALYSIS; POLYHETEROCYCLES; CYCLIZATION; BUTOXIDE;

D O I：

10.1021/acs.orglett.4c02910

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A chemoselective and regioselective copper-promoted defunctionalization procedure has been developed, enabling the rapid construction of various N-polyheterocycles. Initial mechanistic studies reveal that a single-electron transfer radical process is potentially involved.

引用

页码：7744 / 7750

页数：7

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