Defunctionalization Enabled by Intramolecular Radical Aromatic Ipso Substitution

被引：0
|
作者：
Zhang, Qijing [1 ]
Liu, Tinglan [1 ]
Wu, Lili [1 ]
Zhou, Cong-Ying [1 ]
Wang, Chengming [1 ]
机构：
[1] Jinan Univ, Coll Chem & Mat Sci, Guangzhou 511443, Guangdong, Peoples R China
来源：
ORGANIC LETTERS | 2024年 / 26卷 / 36期
关键词：
NITROGEN-HETEROCYCLES; PHOTOREDOX CATALYSIS; POLYHETEROCYCLES; CYCLIZATION; BUTOXIDE;
D O I：
10.1021/acs.orglett.4c02910
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A chemoselective and regioselective copper-promoted defunctionalization procedure has been developed, enabling the rapid construction of various N-polyheterocycles. Initial mechanistic studies reveal that a single-electron transfer radical process is potentially involved.
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页码：7744 / 7750
页数：7
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