Electrodeposition strategies for synthetic highly dispersed Ru-decorated Co (OH)2 nanoneedles as advanced hydrogen evolution reaction catalysts

被引:0
|
作者
Cao, Youjuan [1 ]
Liu, Zhihao [1 ]
Qin, Ningbo [2 ]
Zou, Yongjin [1 ]
Xu, Fen [1 ]
Sun, Lixian [1 ]
Xiang, Cuili [1 ]
机构
[1] Guilin Univ Elect Technol, Guangxi Key Lab Informat Mat, Guilin 541004, Peoples R China
[2] Guangxi Inst Sci & Technol Dev Co Ltd, Nanning 530022, Peoples R China
来源
关键词
Hydrogen evolution reaction; Ru; Co(OH)2; Catalysis; Electrochemical deposition; ELECTROCATALYST; NANOSHEETS;
D O I
10.1016/j.ijoes.2024.100758
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Ru-based nanomaterials have a lot of potential as electrochemical hydrogen evolution reaction (HER) catalysts; however, achieving a uniform dispersion of Ru nanoparticles on substrate materials remains a key challenge. To achieve this, in the current study, we formed NF/Co(OH)2/Ru 2 /Ru by electrodepositing Ru nanoparticles onto Co (OH)2 2 nanoneedles. The Co and O vacancies in the sample promoted water decomposition and the cleavage of OH bonds, while the high surface energies at the apexes of the Co(OH)2 2 nanoneedles supported the even growth and attachment of Ru nanoparticles. In addition, the electron-rich Ru nanoparticles aided in the desorption of hydrogen intermediates. Compared to recently published Ru-based HER materials, the NF/Co(OH)2/Ru 2 /Ru material created in this study shown improved electrochemical characteristics, with an overpotential of 20 mV at 10 mA & sdot;cm- & sdot; cm- 2 and a Tafel slope of 35.43 mV & sdot;dec-1. & sdot; dec- 1 . Therefore, this material and the findings of this study are expected to contribute to HER research.
引用
收藏
页数:8
相关论文
共 50 条
  • [31] Ni-Co-Mo-O nanosheets decorated with NiCo nanoparticles as advanced electrocatalysts for highly efficient hydrogen evolution
    Wen, Shuaiwei
    Yang, Tao
    Zhao, Naiqin
    Ma, Liying
    Liu, Enzuo
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 258
  • [32] Activating Ru-O-Co Interaction on the a-Co(OH)2@Ru Interface for Accelerating the Volmer Step of Alkaline Hydrogen Evolution
    Zhao, Jun
    Wang, Jiajun
    Zheng, Xuerong
    Wang, Haozhi
    Zhang, Jinfeng
    Ding, Jia
    Han, Xiaopeng
    Deng, Yida
    Hu, Wenbin
    SMALL METHODS, 2023, 7 (02):
  • [33] Enhancing the Alkaline Hydrogen Evolution Reaction Activity through the Bifunctionality of Ni(OH)2/Metal Catalysts
    Danilovic, N.
    Subbaraman, Ram
    Strmcnik, D.
    Chang, Kee-Chul
    Paulikas, A. P.
    Stamenkovic, V. R.
    Markovic, Nenad M.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (50) : 12495 - 12498
  • [34] Co(OH)2-Ni(OH)xSy amorphous composite electrocatalysts prepared by electrodeposition method for efficient oxygen evolution reaction
    Xuedong Wei
    Yudan Chai
    Weifeng Chen
    Nan Liu
    Shuangyan Qiao
    Ionics, 2022, 28 : 3945 - 3956
  • [35] Co(OH)2-Ni(OH)xSy amorphous composite electrocatalysts prepared by electrodeposition method for efficient oxygen evolution reaction
    Wei, Xuedong
    Chai, Yudan
    Chen, Weifeng
    Liu, Nan
    Qiao, Shuangyan
    IONICS, 2022, 28 (08) : 3945 - 3956
  • [36] Advanced nanomaterials for highly efficient CO2 photoreduction and photocatalytic hydrogen evolution
    Nautiyal, Rashmi
    Tavar, Deepika
    Suryavanshi, Ulka
    Singh, Gurwinder
    Singh, Archana
    Vinu, Ajayan
    Mane, Gurudas P.
    SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2022, 23 (01) : 866 - 894
  • [37] Surfactant-free colloidal strategies for highly dispersed and active supported IrO2 catalysts: Synthesis and performance evaluation for the oxygen evolution reaction
    Bizzotto, Francesco
    Quinson, Jonathan
    Schroder, Johanna
    Zana, Alessandro
    Arenz, Matthias
    JOURNAL OF CATALYSIS, 2021, 401 : 54 - 62
  • [38] CeO2/Co(OH)2 hybrid electrocatalysts for efficient hydrogen and oxygen evolution reaction
    Sung, Myeong-Chang
    Lee, Gwang-Hee
    Kim, Dong-Wan
    JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 800 : 450 - 455
  • [39] Hydrothermal synthesis of MoS2 nanoflowers as highly efficient hydrogen evolution reaction catalysts
    Wang, Dezhi
    Pan, Zhou
    Wu, Zhuangzhi
    Wang, Zhiping
    Liu, Zhihong
    JOURNAL OF POWER SOURCES, 2014, 264 : 229 - 234
  • [40] Three-dimensional hierarchical Co(OH)F nanosheet arrays decorated by single-atom Ru for boosting oxygen evolution reaction
    Zhou, Shizheng
    Jang, Haeseong
    Qin, Qing
    Li, Zijian
    Kim, Min Gyu
    Li, Chuang
    Liu, Xien
    Cho, Jaephil
    SCIENCE CHINA-MATERIALS, 2021, 64 (06) : 1408 - 1417