Electrodeposition strategies for synthetic highly dispersed Ru-decorated Co (OH)2 nanoneedles as advanced hydrogen evolution reaction catalysts

被引:0
|
作者
Cao, Youjuan [1 ]
Liu, Zhihao [1 ]
Qin, Ningbo [2 ]
Zou, Yongjin [1 ]
Xu, Fen [1 ]
Sun, Lixian [1 ]
Xiang, Cuili [1 ]
机构
[1] Guilin Univ Elect Technol, Guangxi Key Lab Informat Mat, Guilin 541004, Peoples R China
[2] Guangxi Inst Sci & Technol Dev Co Ltd, Nanning 530022, Peoples R China
来源
关键词
Hydrogen evolution reaction; Ru; Co(OH)2; Catalysis; Electrochemical deposition; ELECTROCATALYST; NANOSHEETS;
D O I
10.1016/j.ijoes.2024.100758
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Ru-based nanomaterials have a lot of potential as electrochemical hydrogen evolution reaction (HER) catalysts; however, achieving a uniform dispersion of Ru nanoparticles on substrate materials remains a key challenge. To achieve this, in the current study, we formed NF/Co(OH)2/Ru 2 /Ru by electrodepositing Ru nanoparticles onto Co (OH)2 2 nanoneedles. The Co and O vacancies in the sample promoted water decomposition and the cleavage of OH bonds, while the high surface energies at the apexes of the Co(OH)2 2 nanoneedles supported the even growth and attachment of Ru nanoparticles. In addition, the electron-rich Ru nanoparticles aided in the desorption of hydrogen intermediates. Compared to recently published Ru-based HER materials, the NF/Co(OH)2/Ru 2 /Ru material created in this study shown improved electrochemical characteristics, with an overpotential of 20 mV at 10 mA & sdot;cm- & sdot; cm- 2 and a Tafel slope of 35.43 mV & sdot;dec-1. & sdot; dec- 1 . Therefore, this material and the findings of this study are expected to contribute to HER research.
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页数:8
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